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N80钢在模拟减氧空气驱生产井中的腐蚀行为

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为了探究N80 钢在减氧空气驱生产井中的腐蚀行为,基于灰色关联分析法,分析了国内某减氧空气驱生产井的腐蚀主控因素,并以油藏模拟结果作为室内模拟参数,采用动态失重法结合金相显微镜、XRD、3D形貌等相关表征,研究了不同生产时期N80 钢的腐蚀行为.结果表明:氧含量对减氧空气驱生产井腐蚀的敏感性最大,在含氧工况下,N80 钢的腐蚀速率显著增加,氧含量 3%(0.3 MPa)时的腐蚀速率是不含氧的 5 倍左右.在驱油初期,腐蚀为CO2 主导的局部腐蚀,腐蚀产物主要为致密的FeCO3.随着注气时间的延长,井筒内为CO2/O2 均衡环境,腐蚀转变为二者共同作用,腐蚀产物为FeCO3 和疏松多孔的Fe2O3.在持续注气 3 年后,生产井内为高O2+低CO2 环境,致密的FeCO3 遭到破坏,腐蚀坑横向发展,腐蚀转变为由O2 主导的全面腐蚀.
Corrosion Behavior of N80 Steel in Simulated Oxygen-reduced Air Flooding Production Well
In order to explore the corrosion behavior of N80 steel in oxygen-reduced air flooding production wells,the main controlling factors of corrosion in a domestic oxygen-reduced air flooding production well were analyzed based on the grey relational analysis method.Taking the reservoir simulation results as laboratory simulation parameters,the corrosion behavior of N80 steel in different production periods was studied by dynamic weight loss method combined with metallographic microscope,XRD,3D morphology.The results show that the oxygen content is the most sensitive to the corrosion of the production well with oxygen-reduced air flooding.Under the oxygen containing condition,the corrosion rate of N80 steel increases significantly,and the corrosion rate when the oxygen content is 3%(0.3 MPa),which is about 5 times than that without oxygen.In the initial stage of oil displacement,the corrosion is localized corrosion dominated by CO2,and the corrosion products are mainly dense FeCO3.With the prolongation of gas injection time,the wellbore is in a balanced environment of CO2/O2,and the corrosion transforms into the combined action of the two.The corrosion products are FeCO3 and loose and porous Fe2O3.After 3 years of continuous gas injection,the production well is in a high O2+low CO2 environment,the dense FeCO3 is destroyed,the corrosion pit develops laterally,and the corrosion transforms into a general corrosion dominated by O2.

N80 steeloxygen-reduced air floodingproduction wellboregrey correlation analysisO2/CO2 corrosion

周凯丽、史宝成、薛琨、潘建澎、张兴凯、刘凯、伍丽娟

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长江大学 油气钻采工程湖北省重点实验室,湖北 武汉 430110

N80钢 减氧空气驱 生产井井筒 灰色关联度分析 O2/CO2腐蚀

国家科学自然基金项目油气钻采工程湖北省重点实验室开放基金资助项目

51974033YQZC202103

2024

热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCD北大核心
影响因子:0.55
ISSN:1001-3814
年,卷(期):2024.53(14)