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冷轧Ti-50.8Ni-0.4V形状记忆合金相变和超弹性研究

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利用金相显微镜、示差量热分析法和拉伸试验对比研究了冷轧和退火态Ti-50.8Ni-0.4V合金的相变及超弹性.结果表明:退火处理对冷轧合金的相变和超弹性(SE)特性具有显著的影响.具有大量位错塞积的冷轧态合金表现为线性SE,而退火态合金呈非线性SE,350~550 ℃退火态合金表现为两步相变(A→R→M/M→R→A),形状回复率Rr达到96%,具有优异SE特性.600 ℃和650 ℃退火态合金发生完全再结晶,随温度的升高R相逐渐消失,其相变分别为(A→R→M)/(M→A)和(A→M)/(M→A),形状回复率Rr值<29%,其SE特性明显变差.
Study on Phase Transformation and Superelasticity of Cold Rolled Ti-50.8Ni-0.4V Shape Memory Alloy
The phase transformation and superelasticity of cold rolled and annealed Ti-50.8Ni-0.4Valloys were studied by metallographic microscope,differential calorimetric analysis and tensile test.The results show that annealing treatment has a significant effect on the phase transformation and superelastic(SE)properties of cold rolled alloys.The cold rolled alloy with a large number of dislocation plug product is linear SE,and the annealed alloy is nonlinear SE.The annealed alloy at 350 ℃ shows two-step phase transformation(A→R→M/M →R→ A).The shape recovery rate Rr is 96%,which has excellent SE characteristics.The annealed alloys at 600 ℃ and 650 ℃ are completely recrystallized and the R phase disappears with the increase of temperature.The phase transition is(A→R→M)/(M→A)and(A→M)/(M→ A),respectively.The shape recovery rate Rr is less than 29%,and the SE characteristics become worse obviously.

Ti-50.8Ni-0.4V alloycold rollingmechanical propertiessuperelasticityphase transformationannealing

石海洋、张青来、韩伟东、柏秋生、刘志强

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江苏大学材料科学与工程学院,江苏镇江 212013

宝鸡市博信金属材料有限公司,陕西 宝鸡 721013

Ti-50.8Ni-0.4V合金 冷轧 力学性能 超弹性 相变 退火

2024

热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCD北大核心
影响因子:0.55
ISSN:1001-3814
年,卷(期):2024.53(17)