热加工工艺2024,Vol.53Issue(19) :83-86,92.DOI:10.14158/j.cnki.1001-3814.20223448

硼化物强化铁基堆焊合金组织与性能的研究

Study on Microstructure and Properties of Iron Base Hardfacing Alloy Strengthened by Borides

宗琳 王学昭 徐俊尧 王明
热加工工艺2024,Vol.53Issue(19) :83-86,92.DOI:10.14158/j.cnki.1001-3814.20223448

硼化物强化铁基堆焊合金组织与性能的研究

Study on Microstructure and Properties of Iron Base Hardfacing Alloy Strengthened by Borides

宗琳 1王学昭 1徐俊尧 1王明2
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作者信息

  • 1. 沈阳化工大学 机械与动力工程学院,辽宁 沈阳 110142
  • 2. 中建安装集团有限公司,江苏 南京 210000
  • 折叠

摘要

采用等离子弧堆焊技术在Q235钢基体上制备四组不同B质量分数的Fe-B-Ti-C堆焊合金,分析不同B含量对合金堆焊层的硬质相形态和数量及其性能的影响规律.利用扫描电镜(SEM)、X射线衍射仪(XRD)和维氏硬度计对各堆焊层显微组织和硬度进行测试.结果表明:Fe-B-Ti-C堆焊合金组织由奥氏体(γ)、马氏体(M)、Fe23(C,B)6、Ti(C,B)和Fe2B相构成.随着B含量的增多,堆焊层组织由亚共晶向共晶及过共晶转变,共晶硼化物的形态由蜂窝状向层片状及菊花状转变,且共晶硼化物和Ti(C,B)碳化物的数量也逐渐增多.当B质量分数为7.1%时,过共晶组织中出现大量块状脆性Fe2B初生相,引发了焊接后堆焊层内部裂纹.随着B质量分数的增加,堆焊层表层的显微硬度平均值不断提高,当B质量分数为4.7%时,合金堆焊层顶端显微硬度平均值最高,达到991 HV0.2.

Abstract

Four groups of Fe-B-Ti-C hardfacing alloys with different B mass fraction were prepared on Q235 steel substrate by plasma arc surfacing technology.The influence of different B content on the morphology,quantity of hard phases and properties of the alloy hardfacing layer was analyzed.The microstructure and hardness of each surfacing layer were tested by scanning electron microscopy(SEM),X-ray diffraction(XRD)and Vickers hardness tester.The results show that the microstructure of Fe-B-Ti-C hardfacing alloy is composed of austenite(γ),Martensite(M),Fe23(C,B)6,Ti(C,B)and Fe2B phases.With the increase of B content,the microstructure of the surfacing layer changes from hypoeutectic to eutectic and hypereutectic,the morphology of eutectic borides changes from honeycomb to lamellar and chrysanthemum,and the number of eutectic borides and Ti(C,B)carbides also increases gradually.When the boron content is 7.1%,a large number of blocky brittle Fe2B primary phases appears in the hypereutectic structure,which causes the internal cracks of the surfacing layer after welding.The hardness value of the surfacing layer surface increases with the increase of B mass fraction.When the B mass fraction is 4.7%,the average microhardness of top part of the alloy surfacing layer is the highest,reaching 991 HV0.2.

关键词

等离子堆焊/硼化物/组织/显微硬度

Key words

plasma arc surfacing/borides/microstructure/microhardness

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基金项目

国家自然科学基金青年基金项目(51901141)

辽宁省教育厅科学研究项目(LJ2020034)

出版年

2024
热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCD北大核心
影响因子:0.55
ISSN:1001-3814
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