首页|一种新型钛基钎料钎焊TiAl合金接头的界面组织及性能

一种新型钛基钎料钎焊TiAl合金接头的界面组织及性能

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采用机械球磨制备的TiH2-65Ni和TiB2 复合粉末钎料对Ti-47Al-2Nb-2Cr-0.15B(at%)合金进行钎焊连接,钎焊温度 1190~1250℃、钎焊时间 10 min.研究了TiAl合金钎焊接头界面组织及钎焊温度对接头组织与室温抗剪强度的影响.结果表明,TiAl钎焊接头由 3 个界面反应层组成,主要物相为α2-Ti3Al、τ3-Al3NiTi2、TiB.随着钎焊温度的升高,形成的连续α2-Ti3Al层壁垒被打破,钎料元素向母材的扩散量及母材的溶解量增加,导致钎缝厚度增加.TiAl钎焊接头抗剪强度随钎焊温度的升高先增加后减小.当钎焊温度为 1230℃时,与钎缝基体具有相似的热膨胀系数的TiB晶须尺寸细化,数量增加,层Ⅲ中组织更细化、物相分布更均匀,获得的接头抗剪强度最大,为 332.87 MPa.钎焊接头以准解理断裂方式脆断于以τ3-Al3NiTi2 为主要物相的层Ⅱ中.
Microstructure and Properties of TiAl Alloy Joints Brazed with a Novel Ti-based Filler
TiH2-65Ni and TiB2 composite powder filler prepared by mechanical milling was employed to vacuum braze Ti-47Al-2Nb-2Cr-0.15B(at%)alloy under the brazing temperature of 1190-1250℃for 10 min.The interfacial microstructure of the TiAl alloy brazed joints and the effect of the brazing temperature on the microstructure and the room temperature shear strength of the joint were investigated.It is found that the TiAl brazed joint is divided into three layers and it mainly consists of α2-Ti3Al,τ3-Al3NiTi2 and TiB phases.With the increase of the brazing temperature,the formed continuous α2-Ti3Al layer barrier layer is broken,the dissolution of the filler element into the TiAl substrate and the the dissolution of the TiAl substrate are increased,which results in an increase of brazing seam thickness.With the brazing temperature increasing,the shear strength of the joint increases firstly and then decreases.When the brazing temperature is 1230℃,the aspect ratio and quantity of the TiB whiskers with good thermodynamic compatibility to the brazing seam matrix increase significantly,the microstructure of the layer Ⅲ is refined and the phase distribution is uniformly distributed.The joint presents the maximum shear strength of 332.87 MPa and it brittlely fractures in layer Ⅱ which mainly consists of τ3-Al3NiTi2 in quasi-cleavage mode.

Ti-based powder fillerTiAl alloybrazing temperatureinterfacial microstructureshear strength

冷斌、袁雷昕、王一轩、陈昱橦、罗芬、李力

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江西旅游商贸职业学院 机电与建筑工程学院,江西 南昌 330100

华东交通大学 材料科学与工程学院,江西 南昌 330013

华东交通大学 轨道交通基础设施性能监测与保障国家重点实验室,江西 南昌 330013

钛基粉末钎料 TiAl合金 钎焊温度 界面组织 抗剪强度

2024

热加工工艺
中国船舶重工集团公司热加工工艺研究所 中国造船工程学会船舶材料学术委员会

热加工工艺

CSTPCD北大核心
影响因子:0.55
ISSN:1001-3814
年,卷(期):2024.53(23)