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硼粉对HTPB/AP推进剂性能的影响

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为研究硼粉对HTPB/AP推进剂性能的影响,制备了 3种不同硼粉含量的HTPB/AP推进剂,并使用热重-差示扫描量热仪、密闭爆发器、量热仪和摄像机分别测试了推进剂的热性能、在密闭空间中的燃烧性能、爆热和燃速.结果表明,硼粉改变了 HTPB/AP推进剂试样的热性能,使其热分解温度区间增大;硼粉可显著提高推进剂的爆热和在常压空气中的线性燃速,随着硼粉含量的增加,爆热和在常压空气中的线性燃速也相应增加;硼粉及其含量对推进剂在定容密闭空间中燃烧产生的最大压力影响较小,可显著提高推进剂的平均升压速率,并且随着硼粉含量的增加升压速率也逐渐增加.与空白HTPB/AP推进剂相比,5%、10%和20%硼粉含量的推进剂的爆热分别增加3.5%、11.7%和16%,在常压空气中的线性燃速分别增加9.2%、14.1%和22.6%,在密闭爆发器中燃烧的平均升压速率分别提升 154.5%、181.8%和 218.2%.
Effect of boron powder on properties of HTPB/AP propellant
In order to study the effect of boron powder on properties of HTPB/AP propellant,three kinds of HTPB/AP propellants with different contents of boron powder were prepared.The thermal decomposition properties,combustion behaviors in a cell with a constant-volume,explosion heat and burning rate were tested by TG-DSC,closed bomb test,calorimeter and camera.The results show that the boron powder changes the thermal performance of the propellant and increases the thermal decomposition temperature range of propellant.Boron powder can significantly increase the detonation heat and burning rate in air of propellant.With the increase of boron powder content,the detonation heat and burning rate in air increase accordingly.Boron powder and its content have little influence on the maximum pressure in the closed cell,which can significantly increase the pressurization rate of propellant.With the increase of boron powder content,the pressurization rate gradually increases.Compared with the HTPB/AP propellant,the explosion heat of the propellant with 5%,10%and 20%boron powder increased by 3.5%,11.7%and 16%,the burning rate of the propellant with 5%,10%and 20%boron powder increased by 9.2%,14.1%and 22.6%,the pressurization rate of the propellant with 5%,10%and 20%boron powder increased by 154.5%,181.8%and 218.2%.

boronpropellantthermal performanceexplosion heatcombustion performance

杨洪涛、陈涛、王伦、孙兵兵、张正中

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西安近代化学研究所,西安 710065

硼粉 推进剂 热性能 爆热 燃烧性能

2024

兵器装备工程学报
重庆市(四川省)兵工学会 重庆理工大学

兵器装备工程学报

CSTPCD北大核心
影响因子:0.478
ISSN:2096-2304
年,卷(期):2024.45(12)