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煤矸石动态淋滤中重金属污染物的释放规律研究

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为探究煤矸石在雨水冲刷作用下重金属元素的释放规律及特征,以新疆某采矿区煤矸石为研究对象,采用动态模拟淋滤实验,研究煤矸石中Fe、Mn、Zn和Cu元素的释放规律。结果表明,Fe、Mn、Zn和Cu元素在淋滤前期溶出速率较快,淋出浓度较高,之后随着淋滤时间的延长,各金属元素溶出速率降低,淋出浓度减小,最后趋于稳定,释放达到平衡,整体表现为快速-慢速-平稳释放特征。结合地下水质量标准的要求和各重金属元素在淋滤期内的最大淋滤浓度,该矸石所在地的地下水适用于农业和部分工业用水;金属元素在淋滤期内(8d)的淋出值大小表现为Fe>Mn>Zn>Cu的顺序,Fe元素有相对较强的淋出活性,有向土壤和地下水迁移的潜在风险;矸石中重金属元素的淋滤释放呈指数曲线规律衰减,根据衰减模型可定量预测矸石中重金属在动态淋滤时对土壤和地下水的污染强度。本次实验结果为建立煤矸石堆放条件提供了数据支撑,并为煤矸石堆放场周围水体和土壤的污染治理提供了重要的科学依据。
Study on Leaching Rules of Heavy Metal Pollutants During Dynamic Leaching of Coal Gangue
In order to explore the leaching rules and characteristics of heavy metals in coal gangues by rain erosion,in this paper,coal gangues of a mining area in Xinjiang were taken as the research object and the dynamic simulation leaching experiment is adopted to study on the leaching rules of Fe,Mn,Zn and Cu in coal gangues.The results indicated:the leaching rate was faster and leaching concentration was higher for Fe,Mn,Zn and Cu in the early leaching stage,and as the leaching time elapsed,the dissolution rate of each element decreased,the leaching concentration reduced and finally trended to be stable,and the leaching achieved a balance.To sum up,the overall performance was featured by fast-slow-stable leaching.In combination with the requirements of groundwater quality standards and the maximum leaching concentration of heavy metals during the leaching period,the groundwater in the coal gangue site was suitable for agriculture and some industries.The leaching value of heavy metals during the leaching period(8d)was Fe>Mn>Zn>Cu.Fe had relatively strong leaching activity,but there are potential risks of soil and groundwater migration.The leaching of heavy metals in the coal gangues attenuated in an exponential curve.Therefore,according to the attenuation model,the pollution to soil and groundwater due to heavy metals in coal gangues during dynamic leaching could be quantitatively predicted.The results of this experiment provided data support for determining staking requirements for coal gangue,and created scientific basis for pollution control of water and soil around the coal gangue stacking yard.

Coal gangueheavy metaldynamic leachingleaching concentrationattenuation modelpollution degree

黄蕾、刘伟、殷良俊、黄剑峰、张俊梅

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新疆工程学院化学与环境工程学院,乌鲁木齐 830091

煤矸石 重金属 动态淋滤 淋滤浓度 衰减模型 污染强度

新疆教育厅高等学校基本科研业务费科研项目新疆维吾尔自治区创新训练项目新疆工程学院博士启动金项目

XJEDU2023P135S2022109940362018xgy062105

2024

四川环境
四川省环境保护科学研究院 四川省环境科学学会

四川环境

CSTPCD
影响因子:0.444
ISSN:1001-3644
年,卷(期):2024.43(2)
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