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成都市锦江流域抗生素污染特征及生态风险

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采用固相萃取-高效液相色谱/串联质谱法分析了成都市锦江流域主要河流中枯水期和丰水期的抗生素污染组成,涉及6类共26种抗生素,并采用风险熵值法评估了锦江流域中20种抗生素的生态风险。结果表明:锦江流域河流中共检测出6类25种抗生素,其中β-内酰胺类污染浓度最高,浓度范围为314~716 ng/L。河流中抗生素浓度受季节影响,表现出枯水期污染浓度高于丰水期的趋势。锦江流域中青霉素G、阿莫西林、头孢噻肟、磺胺甲恶唑、沙拉沙星和脱水红霉素表现为高风险,氨苄青霉素、红霉素、罗红霉素、氧氟沙星和磺胺二甲嘧啶表现为中风险,其余抗生素为低风险。
Contamination Characteristics and Risk Assessment of Antibiotics in Jinjiang River Basin of Chengdu
The composition of antibiotic contamination in the main rivers of the Jinjiang River Basin in Chengdu during the dry and abundant periods was analyzed with the solid-phase extraction-high performance liquid chromatography-tandem mass spectrometry,involving 26 antibiotics of 6 categories,and the ecological risk of 20 antibiotics in the Jinjiang River Basin was assessed by the risk entropy value method.The results showed that 25 antibiotics of 6 categories were detected in the Jinjiang River Basin,among which β-lactams had the highest concentration,ranging from 314 ng/L to 716 ng/L.The concentration of antibiotics in the river was influenced by the season,showing a trend that the pollution concentration was higher in the dry period than in the abundant period.Penicillin G,amoxicillin,cefotaxime,sulfamethoxazole,sarafloxacin and dehydrated erythromycin in the Jinjiang River Basin showed high risk,ampicillin,erythromycin,roxithromycin,ofloxacin and sulfadimethoxine showed medium risk,and the rest of antibiotics showed low risk.

HPLC-MSChengduJinjiang Riverrisk assessmentantibiotics

唐文雅、竺美、毛淑娟、黄冬梅、林鑫

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四川省生态环境科学研究院,成都 610041

超高效液相色谱/串联质谱 成都市 锦江 风险评估 抗生素

四川省科技厅基本科研业务费项目

2022JDKY0021

2024

四川环境
四川省环境保护科学研究院 四川省环境科学学会

四川环境

CSTPCD
影响因子:0.444
ISSN:1001-3644
年,卷(期):2024.43(5)