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氧化石墨烯的制备及吸附微囊藻毒素特性研究

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微囊藻毒素(Microcystin,MCs)分布广泛,对生态环境和人类健康造成潜在威胁,常规方法对其去除效果有限。氧化石墨烯(Graphene oxide,GO)作为石墨烯的重要衍生物之一,在吸附水中有机物、重金属离子方面表现出良好的吸附性能。通过Hummer法制备GO,并利用扫描电镜(SEM)对GO进行表征,阐明其吸附机理;同时研究了pH值、接触时间、初始浓度和可溶性有机物(DOM)对GO吸附MC-LR的影响。结果表明GO对MC-LR具有良好的吸附性能,吸附等温线符合Langmuir等温线模型,表明吸附属于单层吸附;此外,pH值、不同阴离子和DOM都会对吸附产生干扰。本实验为解决MCs在环境中的危害提供了一些新的想法和思路。
Preparation of Graphite Oxide and Its Adsorption Properties for Microcystins
Microcyst ins(MCs)are widely distributed and pose potential threats to the ecological environment and human health.Conventional methods have limited effect on removing it.Graphene oxide(GO),a significant derivative of graphene,exhibits excellent adsorption properties for organic matter and heavy metal ions in water.GO was prepared by the Hummer method and characterized through the scanning electron microscopy(SEM)to explain its adsorption mechanism.Additionally,the impacts of pH,contact time,initial concentration,and dissolved organic matter(DOM)on GO adsorption of MC-LR were investigated.The results revealed that GO exhibited good adsorption performance for MC-LR,with the adsorption isotherm conforming to the Langmuir model,indicating monolayer adsorption.What's more,pH,different anions,and DOM can interfere with the adsorption process.This experiment offers new ideas and approaches for addressing the environmental hazards of MCs.

Graphene oxidemicrocystinsadsorption

宋芳琪、王华生、姚灿、汪辉、范娇

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江西理工大学土木与测绘工程学院,江西赣州 341000

氧化石墨烯 微囊藻毒素 吸附

2024

四川环境
四川省环境保护科学研究院 四川省环境科学学会

四川环境

CSTPCD
影响因子:0.444
ISSN:1001-3644
年,卷(期):2024.43(6)