首页|Fe-Si-B非晶合金电极在电芬顿法处理模拟港口含油废水中的应用

Fe-Si-B非晶合金电极在电芬顿法处理模拟港口含油废水中的应用

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根据港口含油废水的组成,配置了含有乳化油等污染物的模拟废水,考察了Fe-Si-B非晶合金作为电芬顿体系中的阳极在降解乳化油废水中的情况,分别考察了反应时间、电流密度、初始pH值、H2 O2投加量对反应的影响,并优化了工艺参数.实验结果表明:在反应时间为 40 min、电流密度为 30 mA/cm2、初始pH值为3、H2 O2 浓度为20g/L时,废水含油量去除率可达到99.91%.分析推测了电芬顿法降解乳化油废水的可能反应途径,结果表明:电芬顿体系中产生的羟基自由基的强氧化作用下将原本废水中的长链有机物部分氧化为易被生物降解的短链烷烃类有机物.为含乳化油废水的处理以及Fe-Si-B非晶合金作为电极材料的实际应用提供了良好的参考价值.
Application of Fe-Si-B amorphous alloy electrode in the treatment of simulated port oily wastewater by electro-fenton method
Simulated wastewater including contaminants such as emulsified oil was created based on the composition of oily wastewater at ports.The performance of an anode made of Fe-Si-B amorphous alloy in an electro-fenton system for decomposing emulsified oil effluent was examined.The effects of current density,starting pH,and H2 O2 dose on the reaction were studied,and process parameters were modified.The experimental findings reveal that when the reaction period is 40 minutes,the current density is 30 mA/cm2,the starting pH value is 3,and the H2 O2concentrationis20 g/L,theoilremovalrateofwastewatermayreach99.91%.Thepossiblereaction pathway for the electro-fenton method's degradation of emulsified oil wastewater was analyzed.And the results shows that the strong oxidation of hydroxyl radicals generated in the electrio-fenton system partially oxidizes the original wastewater's long-chain organic compounds into easily biodegradable short chain alkanes.This gives a solid starting point for the treatment of emulsified oil-containing wastewater and the practical application of Fe-Si-B amorphous alloy as an electrode material.

electro-fentonoily wastewaterFe-Si-B amorphous alloy

王廷沣、赵英杰、叶伟、赵俊杰、常方、李振东、李慧婷、仪马兰

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交通运输部天津水运工程科学研究所,天津 300456

电芬顿 乳化油废水 Fe-Si-B非晶合金

中央级公益性科研院所基本科研业务费专项资金项目

TKS20210211

2024

水道港口
交通部天津水运工程科学研究所

水道港口

CSTPCD
影响因子:0.348
ISSN:1005-8443
年,卷(期):2024.45(3)
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