山东化工2024,Vol.53Issue(2) :232-235,238.

"双碳"背景下废弃生物质的高值化利用研究

Research on High-value Utilization of Waste Biomass under Carbon Peaking

邵俊 郭丰艳 刘建朋 包坤 郝斌
山东化工2024,Vol.53Issue(2) :232-235,238.

"双碳"背景下废弃生物质的高值化利用研究

Research on High-value Utilization of Waste Biomass under Carbon Peaking

邵俊 1郭丰艳 1刘建朋 2包坤 1郝斌1
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作者信息

  • 1. 唐山学院新材料与化学工程学院,河北唐山 063000
  • 2. 唐钢国际工程技术有限公司,河北唐山 063000
  • 折叠

摘要

以废弃棉花秸秆为原料,在500 ℃下热解制备了棉花秸秆活性炭(CSAC),并研究了对亚甲基蓝和酸性品红的吸附特性.同时,以CSAC为载体,采用水热法制备ZnO/CSAC,并初步探索其光催化特性.结果表明:室温下,投加量为6,25 g/L,吸附60,90 min时,CSAC对200 mg/L模拟亚甲基蓝和酸性品红废水的脱色率分别为99.66%和78.20%.对两种染料的吸附过程都更符合准二级动力学,受化学吸附控制,且为放热过程.可见光照射下,ZnO/CSAC的投加量为1 g/L,2h时对200 mg/L亚甲基蓝的降解率可以达到91.20%.ZnO/CSAC中纳米ZnO呈二维片状组装成绒球状长在CSAC表面,活性反应点位增多,光催化性能良好.

Abstract

CSAC was prepared from waste cotton straw through pyrolysis method at 500 ℃.The adsorption properties of methylene blue and acid fuchsin were studied.At the same time,ZnO/CSAC was prepared by hydrothermal method using CSAC as carrier,and its photocatalytic properties were preliminarily investigated.The results showed that at room temperature,the decolorization rates of 200 mg/L simulated methylene blue and acid fuchsin wastewater were 99.66%and 78.20%,respectively,at the dosage of 6 g/L and 25 g/L,and at the adsorption time of 60 min and 90min.The adsorption process of the two dyes conforms to the quasi-second-order kinetics,is controlled by chemisorption,and is exothermic.Under visible light irradiation,ZnO/CSAC dosage is 1 g/L,and the degradation rate of 200 mg/L methylene blue can reach 91.20%after 2 h.In ZnO/CSAC,nano-zno is assembled into spheroids in two-dimensional sheets and grows on the surface of CSAC,with more active reaction sites and good photocatalytic performance.

关键词

废弃生物质/高值化/染料/光催化

Key words

waste biomass/high-value utilization/dyes/photocatalysis

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基金项目

河北省无机非金属材料实验室开放基金(HLINM202203)

唐山市社会科学发展课题(2023)(TSSKL2023-244)

唐山市软科学研究计划(22110205F)

唐山市水环境绿色降解新材料基础创新团队项目(22130218G)

河北省科技特派员项目(2023)()

出版年

2024
山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
参考文献量11
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