首页|"双碳"背景下废弃生物质的高值化利用研究

"双碳"背景下废弃生物质的高值化利用研究

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以废弃棉花秸秆为原料,在500 ℃下热解制备了棉花秸秆活性炭(CSAC),并研究了对亚甲基蓝和酸性品红的吸附特性。同时,以CSAC为载体,采用水热法制备ZnO/CSAC,并初步探索其光催化特性。结果表明:室温下,投加量为6,25 g/L,吸附60,90 min时,CSAC对200 mg/L模拟亚甲基蓝和酸性品红废水的脱色率分别为99。66%和78。20%。对两种染料的吸附过程都更符合准二级动力学,受化学吸附控制,且为放热过程。可见光照射下,ZnO/CSAC的投加量为1 g/L,2h时对200 mg/L亚甲基蓝的降解率可以达到91。20%。ZnO/CSAC中纳米ZnO呈二维片状组装成绒球状长在CSAC表面,活性反应点位增多,光催化性能良好。
Research on High-value Utilization of Waste Biomass under Carbon Peaking
CSAC was prepared from waste cotton straw through pyrolysis method at 500 ℃.The adsorption properties of methylene blue and acid fuchsin were studied.At the same time,ZnO/CSAC was prepared by hydrothermal method using CSAC as carrier,and its photocatalytic properties were preliminarily investigated.The results showed that at room temperature,the decolorization rates of 200 mg/L simulated methylene blue and acid fuchsin wastewater were 99.66%and 78.20%,respectively,at the dosage of 6 g/L and 25 g/L,and at the adsorption time of 60 min and 90min.The adsorption process of the two dyes conforms to the quasi-second-order kinetics,is controlled by chemisorption,and is exothermic.Under visible light irradiation,ZnO/CSAC dosage is 1 g/L,and the degradation rate of 200 mg/L methylene blue can reach 91.20%after 2 h.In ZnO/CSAC,nano-zno is assembled into spheroids in two-dimensional sheets and grows on the surface of CSAC,with more active reaction sites and good photocatalytic performance.

waste biomasshigh-value utilizationdyesphotocatalysis

邵俊、郭丰艳、刘建朋、包坤、郝斌

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唐山学院新材料与化学工程学院,河北唐山 063000

唐钢国际工程技术有限公司,河北唐山 063000

废弃生物质 高值化 染料 光催化

河北省无机非金属材料实验室开放基金唐山市社会科学发展课题(2023)唐山市软科学研究计划唐山市水环境绿色降解新材料基础创新团队项目河北省科技特派员项目(2023)

HLINM202203TSSKL2023-24422110205F22130218G

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(2)
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