首页|3-氟-苯硼酸修饰PEDOT电化学检测乳酸和葡萄糖

3-氟-苯硼酸修饰PEDOT电化学检测乳酸和葡萄糖

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通过将含 3-氟苯硼酸的 3,4-乙烯二氧噻吩(EDOT-FPBA)单体在玻碳电极上以恒定电压进行电聚合,构筑PEDOT-FPBA电极,通过调节被测溶液的pH值选择性识别葡萄糖和乳酸。利用扫描电子显微镜和电化学阻抗法进行表征,通过电化学阻抗法在pH值为 2或7 的条件下分别对葡萄糖或乳酸进行检测,线性范围为 0。05~30 mmol/L,检测限(LOD)为 0。03 mmol/L。此外,PEDOT-FPBA作为一种不同pH值条件下葡萄糖及乳酸传感,具有宽检测范围、良好的选择性、存储稳定性和可重复使用等优点,在无酶葡萄糖、乳酸连续监测应用中具有巨大的潜力。
3-fluorobenzoborate Modified PEDOT for the Electrochemical Detection of Lactic Acid and Glucose
The PEDOT-FPBA electrode was constructed by electropolymerization of 3,4-ethylenedioxythiophene(EDOT-FPBA)monomer containing 3-fluorobenylboric acid on a glass carbon electrode at constant voltage,and the glucose and lactic acid were selectively identified by adjusting the pH of the tested solution.It was characterized by scanning electron microscopy and electrochemical impedance method.Glucose or lactic acid were detected by electrochemical impedance method at pH value 2 or 7,respectively,with a linear range of 0.05 to 30 mmol/L and a detection limit(LOD)of 0.03 mmol/L.In addition,PEDOT-FPBA,as a kind of glucose and lactic acid sensor under different pH conditions,has the advantages of wide detection range,good selectivity,storage stability and reuse,and has great potential in the continuous monitoring of enzyme-free glucose and lactic acid.

glucoselactic acidelectrochemistrysensor

陈志冉、李丽娟、刘洋、白婷芳、海文峰

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内蒙古民族大学 化学与材料学院,内蒙古 通辽 028000

葡萄糖 乳酸 电化学 传感器

国家自然科学基金内蒙古自治区高等学校青年科技英才支持计划内蒙古自治区科技计划

22164016NJYT230342022YFSH0040

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(3)
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