山东化工2024,Vol.53Issue(4) :18-21.

MOF衍生的Co-CNT纳米片阵列高效催化氢气析出反应

MOF Derived Co-CNT Nanosheet Array as Efficient Electocatalyst for Hydrogen Evolution Reaction

张兴云 朱子娴 王小稹 刘亚群 王敏 张祥
山东化工2024,Vol.53Issue(4) :18-21.

MOF衍生的Co-CNT纳米片阵列高效催化氢气析出反应

MOF Derived Co-CNT Nanosheet Array as Efficient Electocatalyst for Hydrogen Evolution Reaction

张兴云 1朱子娴 1王小稹 1刘亚群 1王敏 1张祥1
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作者信息

  • 1. 临沂大学化学化工学院,山东临沂 276000
  • 折叠

摘要

制备便宜、活性高的催化剂以实现高效地氢气析出反应具有较高挑战性.以自支撑的Co金属有机框架为前驱体,通过一步碳化制备了泡沫镍支撑的嵌入了 Co纳米粒子的碳纳米管组成的纳米片阵列(简写为Co-CNT/NF).该Co-CNT/NF在碱性条件下展现了良好的催化氢气析出反应性能.当传递10 A·cm-2的电流时,Co-CNT/NF仅需-134 mV的过电势,且催化活性至少可以保持12 h.较小的电阻和丰富的催化位点是导致Co-CNT/NF高催化活性的主要因素.这种简便、高效的催化剂合成方法,将为金属有机框架衍生的新型催化剂开发及在能源存储方面的应用提供新启发.

Abstract

Developing inexpensive and efficient electrocatalysts for hydrogen evolution reaction remains an important but challenging issue.In this work,the self-supporting Co-metal organic framework was used as the precursor to prepare the Co nanoparticles embedded carbon nanotubes nanosheet array on the nickel foam(abbreviated as Co CNT/NF)through a one-step carbonization.The Co CNT/NF exhibits excellent catalytic performance towards hydrogen evolution reaction under alkaline conditions.When delivering a current of 10 A·cm-2,Co CNT/NF only requires an overpotential of-134 mV.And the catalytic activity can be maintained for at least 12 h.The combination of smaller resistance and abundant catalytic sites results in its excellent catalytic performance.This simple and efficient synthesis method will provide new inspiration for the development of new catalysts derived from metal organic frameworks and their applications in energy storage.

关键词

金属有机框架/钴纳米粒子/碳纳米管/电催化/氢气析出反应

Key words

metal organic framework/cobalt nanoparticles/carbon nanotubes/electrocatalysis/hydrogen evolution reaction

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基金项目

山东省大学生创新创业训练计划项目(S202310452107)

出版年

2024
山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
参考文献量10
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