山东化工2024,Vol.53Issue(4) :33-36.

含苯并咪唑基团的可溶性聚酰亚胺粉体的合成及性能

Synthesis and Properties of Soluble Polyimide Powders Containing 1H-Benzimidazole Groups

陈益 胡锦平 吴建华
山东化工2024,Vol.53Issue(4) :33-36.

含苯并咪唑基团的可溶性聚酰亚胺粉体的合成及性能

Synthesis and Properties of Soluble Polyimide Powders Containing 1H-Benzimidazole Groups

陈益 1胡锦平 1吴建华1
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作者信息

  • 1. 常州市尚科新材料有限公司,江苏常州 213134
  • 折叠

摘要

2-(4-氨基苯基)-5-氨基苯并咪唑(APBIA)与双酚二醚二酐(BPADA)在N,N-二甲基乙酰胺(DMAC)中均聚,然后进行化学亚胺化得到可溶性聚酰亚胺树脂溶液,将此溶液在高压匀质机中加乙醇成粉,抽滤,洗涤,烘干后对其结构、热稳定性、力学性能进行了研究.结果表明:苯并咪唑基团的引入提高了聚酰亚胺的耐热性,双酚二醚二酐单元的引入提高了聚酰亚胺的溶解性及韧性,是一种兼顾溶解性和力学性能的新型聚酰亚胺材料.

Abstract

2-(4-aminophenyl)-5-aminobenzimidazole(APBIA)and bisphenol diether dianhydride(BPADA)were homopolymerized in N,N-dimethylacetamide(DM AC),and then imidized chemically to obtain a soluble polyimide resin solution,then adding ethanol into powders in a high-pressure homogenizer,the structure,thermal stability and mechanical properties of the polyimide were studied after filtering,washing and drying.The results showed that the introduction of 1H-benzimidazole group improved the heat resistance of the polyimide,and the introduction of bisphenol diether dianhydride unit improved the solubility and toughness of the polyimide,it is a new type of polyimide material with both solubility and mechanical properties.

关键词

聚酰亚胺/热性能/力学性能

Key words

polyimide/thermal properties/mechanical properties

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出版年

2024
山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
参考文献量8
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