山东化工2024,Vol.53Issue(4) :265-269.

羟丙基-β-环糊精/臭氧包络物氧化降解多种有机物研究

Oxidative Degradation of a Variety of Organic Compounds by Hydroxypropyl-β-Cyclodextrin/Ozone Envelopes

蒋维洋 聂瑶 唐俊辉 王涛
山东化工2024,Vol.53Issue(4) :265-269.

羟丙基-β-环糊精/臭氧包络物氧化降解多种有机物研究

Oxidative Degradation of a Variety of Organic Compounds by Hydroxypropyl-β-Cyclodextrin/Ozone Envelopes

蒋维洋 1聂瑶 1唐俊辉 1王涛1
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作者信息

  • 1. 西华师范大学环境科学与工程学院,四川南充 637009
  • 折叠

摘要

为延长臭氧的半衰期,保留其选择氧化性,通过羟丙基-β-环糊精与臭氧包络的方式.研究了臭氧/羟丙基-β-环糊精包络物(O3/CD)的氧化特性,研究对比了两种不同液相制备方法制备包络物的氧化性能,探究了 O3/CD对靛蓝三磺酸盐(indigo)、2,2-联氮-双-(3-乙基-苯并噻唑啉-6-磺酸)二胺盐(ABTS)以及甲基橙(MO)的氧化特性,O3/CD能够延长臭氧的半衰期,并提高其氧化性,在环糊精溶液中通入臭氧的氧化性明显优于文献报道的方式,在通入饱和臭氧下,表现出较高的氧化性能,向0.5 mmol/L的环糊精溶液中通入10 mg/L的臭氧后,对Indigo、ABTS和MO均表现出较强的持续氧化能力,为水体和土壤污染物氧化修复提供了新的路径.

Abstract

In order to prolong the half-life of ozone and retain its selective oxidation,hydroxypropyl-β-cyclodextrin is enveloped with ozone.The oxidation properties of ozone/hydroxypropyl-β-cyclodextrin envelopes(O3/CD)were studied,the oxidation properties of the envelopes prepared by two different liquid phase preparation methods were studied,and the oxidation properties of O3/CD against indigo trisulfonate(indigo),2,2-azazolidine-bis-(3-ethyl-benzothiazoliline-6-sulfonic acid)diamine salt(ABTS)and methyl orange(MO)were studied,and O3/CD could prolong the half-life and improve the oxidation of ozone.The oxidation of ozone introduced into the cyclodextrin solution is significantly better than that reported in the literature,and it shows high oxidation performance under the introduction of saturated ozone,and after the introduction of 10 mg/L ozone into the cyclodextrin solution of 0.5 mmol/L,it shows strong continuous oxidation ability to Indigo,ABTS and MO,which provides a new path for the oxidative remediation of water and soil pollutants.

关键词

臭氧/氧化/羟丙基-β-环糊精/包络物

Key words

ozone/oxidation/hydroxypropyl-β-cyclodextrin/envelopes

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基金项目

四川省科技计划项目(2018JY0221)

四川省科技计划项目(17E058)

出版年

2024
山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
参考文献量16
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