首页|基于荧光光谱法的Cryptophane-E-Me@氯仿络合作用研究

基于荧光光谱法的Cryptophane-E-Me@氯仿络合作用研究

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报道了含甲基取代的cryptophanes合成方法,并用荧光光谱法研究了其对氯仿的识别性能。其中cryptophane-E-Me与氯仿有更强的络合作用,其络合常数为 480。5 L·mol-1。这种cryptophane-E-Me与氯仿间较强及稳定的络合作用提供了一种方便、环保的痕量氯仿检测方法。
Complexation of Cryptophane-E-Me@Chloroform Based on Fluorescence Spectrometry
The synthesis of cryptophanes with methyl substitutions was described,and recognition properties for chloroform were investigated by fluorescence spectrometry.Cryptophane-E-Me was prior for chloroform capture with a binding constant of 480.5 L·mol-1,and the strong and stable complexation between chloroform and cryptophane-E-Me provided a convenient and enviromental friendly method for trace chloform detection.

cryptophanechloroformfluorescence spectrometrymolecular recognition

贾君瑶、高元喆、陈晓雨、吴警、庄佳树、尹永恒、李昱

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临沂大学化学化工学院,山东临沂 276005

cryptophane 氯仿 荧光光谱法 分子识别

山东省自然科学基金

ZR2020QB039

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(5)
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