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一种甲维盐废盐预处理方法研究

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甲氨基阿维菌素苯甲酸盐(简称甲维盐)是一种广谱、高效的杀虫剂,其生产过程会用到有机缚酸剂四甲基乙二胺,并产生相应的危废四甲基乙二胺盐酸盐(即甲维盐废盐),该危废氯含量高(28。15%),焚烧处置时产生大量氯化氢,对环保耗材消耗、烟气排放和设备腐蚀影响均较大。本文采用甲维盐与另一种含有机钾盐废催化剂协同预处理的方式,改变可燃氯元素状态,降低焚烧过程氯化氢气体产生量,减少环保耗材消耗,减轻设备腐蚀,达到降本增效的目的。考察了碱的种类、反应温度、时间和溶剂量等条件对可燃氯脱除率的影响,在用含有机钾盐废催化剂作为可燃氯脱除剂、温度 25℃、反应时间 20 min和溶剂量 0。4 mL/g的条件下,可燃氯脱除率可达到84。2%,基本可达到氢氧化钠脱除效果。该方法对此类危废的预处理具有一定借鉴作用。
Study on a Pretreatment Method for Waste Salt of Emamectin Benzoate
Emamectin benzoate is a broad-spectrum and highly effective insecticide.Its production process uses tetramethylethylenediamine as the acid-acceptor,which produces the corresponding tetramethylethylenediamine hydrochloride as hazardous waste(i.e.waste salt of emamectin benzoate).The hazardous waste has a high chlorine content(28.15%)and generates a large amount of hydrogen chloride during incineration,which has a significant impact on production equipment and environmental protection.This article adopts a collaborative pretreatment method with another type of hazardous waste to change the state of combustible chlorine elements,which reduce the production of hydrogen chloride,consumable material and equipment corrosion,reduce production costs and improve production efficiency during this process.This article investigates the effects of alkali types,reaction temperature,time and solvent amount on the removal rate of combustible chlorine.Under the conditions of using waste catalysts containing organic potassium salts as combustible chlorine removal agents,temperature 25℃,reaction time 20 minutes,and solvent amount 0.4 mL/g,the removal rate of combustible chlorine can reach 84.2%,basically achieving the removal effect of sodium hydroxide.This method has a certain reference value for the pretreatment of such hazardous waste.

tetramethylethylenediamine hydrochlorideemamectin benzoatecombustible chlorinehazardous wastepretreatment

尤洪星、颜廷学、刘长宇、谢登龙

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光大绿色环保危废处置(临沭)有限公司,山东临沭 276700

四甲基乙二胺盐酸盐 甲维盐 可燃氯 危险废物 预处理

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(5)
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