多孔有机笼的构建及应用进展
Construction and Application of Porous Organic Cage
孔启迪1
作者信息
- 1. 烟台大学 环境与材料工程学院,山东 烟台 264005
- 折叠
摘要
多孔有机笼(Porous Organic Cages,POCs)是一类具有独特优势的低密度新型晶态多孔材料,由笼状离散分子组成,拥有可设计性的开放空腔或孔道,具备良好的气体渗透性和液体可溶性,以及高的稳定性和永久孔隙度.由于POCs材料的稳定多孔性质和溶解度优势,拓宽了其应用范围,POCs材料目前已被设计、构建并应用于气体储存和分离、选择性客体包合、吸附、环境净化以及多相催化等多种领域.基于此,针对近年来POCs材料的构建及应用进展进行重点阐述.
Abstract
Porous Organic Cages(POCs)are a new class of low density crystalline porous materials with unique advantages,consisting of caged discrete molecules with designable open cavities or channels,good gas permeability and liquid solubility,as well as high stability and permanent porosity.Due to the stable porous properties and solubility properties of POCs,its application range has been broadened.Currently,POCs materials have been designed,constructed and applied in various fields such as gas storage and separation,selective guest inclusion,adsorption,environmental purification and heterogeneous catalysis.Based on this,this paper will focus on the construction and application progress of POCs materials in recent years.
关键词
多孔材料/晶体材料/共价键/吸附Key words
porous material/crystal material/covalent bond/adsorption引用本文复制引用
出版年
2024
NETL
NSTL
万方数据