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微波辅助回收废旧锂电池石墨的研究进展

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在实现国家"双碳"目标的背景下,锂电池市场发展迅猛,随之带来的问题是废旧锂电池数量逐渐增加,因此对于废旧锂电池的回收利用是一项紧迫而必要的任务。然而,目前市场只注重回收有价值的金属,石墨材料通常被丢弃或作为燃料燃烧,造成有价值的碳材料被大量浪费。由于石墨具有优异的微波吸收能力和导电性,微波辐射在废旧石墨上产生焦耳热放电-等离子体耦合效应,这种特殊的功能能够以有效的方式帮助去除杂质,结构修复和石墨嵌入和剥落。因此,本文综述了微波辅助去除杂质,修复受损石墨结构的进展,并讨论了微波辅助制备膨胀石墨、石墨烯及石墨烯基材料等方面的突破。旨在为废旧石墨的增值资源利用和新型储能材料的制备提供参考,以促进电池产业的可持续发展。
Progress on the Micro wave-Assisted Recycling of Spent Lithium Battery Graphite
In the context of the realization of the national"dual-carbon"goal,the lithium battery market momentum is developing rapidly,and the accompanying problem is the gradual increase in the number of spent lithium batteries.Therefore,the recycling of spent lithium batteries is an urgent and necessary task.However,the current market only focuses on the recovery of valuable metals,and graphite materials are usually discarded or burned as fuel,resulting in a large amount of valuable carbon materials being wasted.Due to the excellent microwave absorption capacity and conductivity of graphite,microwave radiation generates Joule thermal discharge-plasma coupling effect on spent graphite.This special function can help remove impurities,structural repair and graphite embedding and peeling in an effective way.Therefore,this paper reviews the progress of microwave-assisted removal of impurities and repair of damaged graphite structure,and discusses the breakthroughs in microwave-assisted preparation of expanded graphite,graphene and graphene-based materials,porous graphene and so on.It aims to provide a reference for the utilization of value-added resources of spent graphite and the preparation of new energy storage materials,so as to promote the sustainable development of the battery industry.

microwavespent graphiteimpurity removalexpanded graphitegraphene

乔自鹏、朱建楠、马守肖、姚送送

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浙江南都电源动力股份有限公司,浙江杭州 310012

安徽南都华铂新材料科技有限公司,安徽阜阳 236500

微波 废旧电池 杂质去除 膨胀石墨 石墨烯

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(12)
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