首页|UiO-66-NH2纳米纤维复合膜的制备和吸附应用研究

UiO-66-NH2纳米纤维复合膜的制备和吸附应用研究

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水溶性染料等有机污染物广泛分布于土壤和水中,对生态系统造成严重破坏。本工作采用原位溶剂热法将水稳定的锆基金属-有机框架(UiO-66-NH2)负载到有机-无机杂化电纺纤维膜上。这种新型复合膜具有比表面积大、吸附性能好等优点。考察了复合膜对亚甲基蓝(MB)、罗丹明B(RhB)以及荧光素钠(SF)的吸附性能。最大吸附容量分别为:MB为64。5 mg/g,RhB为34。4 mg/g,SF为70。08 mg/g。在外加剂过硫酸盐作用下,UiO-66-NH2基纳米纤维复合膜能够较快降解吸附的染料并恢复其吸附性能,且操作简便、重复利用率高,在废水净化方面有很好的应用前景。
Preparation and Utilization of UiO-66-NH2 Nanofiber Composite Membrane for Adsorption Purposes
Organic pollutants such as water-soluble dyes are widely distributed in soil and water,causing serious damage to the ecosystem.In this work,a water-stable zirconium-based metal-organic framework(UiO-66-NH2)was loaded onto an organic-inorganic hybrid electrospun fiber membrane by an in situ solvothermal method.This new composite membrane has the advantages of large specific surface area and good adsorption performance.The adsorption performance of the composite membrane for methylene blue(MB),rhodamine B(RhB)and sodium fluorescein(SF)was investigated.The maximum adsorption capacities were 64.5 mg/g for MB,34.4 mg/g for RhB,and 70.08 mg/g for SF.Under the action of the admixture persulfate,the UiO-66-NH2-based nanofiber composite membrane can quickly degrade the adsorbed dyes and restore their adsorption performance.It is easy to operate and has a high reuse rate.It has a good application prospect in wastewater purification.

metal-organic frameworkselectrospun fiber membranesadsorptionphotocatalytic degradationregeneration

黄继明、刘润清、何炳林、袁剑国、李方庆、李莲、王清宇、张桂英

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铜仁学院材料与化学工程学院,贵州铜仁 554300

金属有机框架材料 电纺纤维膜 吸附 光催化降解 再生

铜仁学院博士启动基金大学生创新创业训练项目

trxyDH2202202210665077

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(14)