首页|钼反萃取三相物中铀钼回收技术研究

钼反萃取三相物中铀钼回收技术研究

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某铀钼矿从含钼酸性浸出液中萃取钼,在氨水反萃取钼的过程中产生大量萃取三相物,根据该三相物渣的物质组成及铀钼存在形式,进行了铀钼回收提取的试验研究。试验结果表明,在同一体系下难以实现铀、钼的一步提取,采用"先水浸钼,再酸浸铀"分步处理工艺可以实现铀、钼的高效提取。扩大试验验证了分步处理工艺的可行性,并且考察了采用板框压滤可以取得较好的效果,铀浸出率可达到98。93%,钼浸出率可达到96。08%,所得含钼溶液与酸沉母液合并后再萃取钼、含铀溶液与铀萃原液合并后再萃取铀,从而实现了与工业生产的有机结合,避免了溶液中有机相及铵根离子对氧压浸出生产系统的影响。
Research on Uranium and Molybdenum Recovery Technology in Molybdenum Back Extraction Three-Phase Compound
A uranium molybdenum mine extracts molybdenum from the acid leaching solution containing molybdenum,and a large number of extracted three-phase substances are produced in the process of ammonia reverse extraction of molybdenum.According to the material composition of the filter residue and the existing form of uranium and molybdenum,the experimental study on the recovery and extraction of uranium and molybdenum is carried out.The experimental results show that it is difficult to extract uranium and molybdenum in one step under the same system.The step-by-step treatment process of"first water leaching molybdenum and then acid leaching uranium"can achieve the efficient extraction of uranium and molybdenum.The feasibility of the step-by-step treatment process is verified by the expanded test,and it is investigated that the plate and frame pressure filtration can achieve good results.The uranium leaching rate can reach 98.93%and the molybdenum leaching rate can reach 96.08%.The obtained molybdenum containing solution is combined with the acid precipitation mother liquor and then molybdenum is extracted,and the uranium containing solution is combined with the uranium extraction mother liquor and then uranium is extracted,so as to realize the organic combination with industrial production,The influence of organic phase and ammonium ion in solution on oxygen pressure leaching production system is avoided.

uranium molybdenum oreback extractionthird-phase compoundexpanding testfiltration and washing

刘永涛、刘辉、隋杰、师留印、程瑞泉、贾秀敏、高东星、刘硕、霍玉宝

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中核沽源铀业有限责任公司,河北张家口 076561

核工业北京化工冶金研究院,北京 101149

铀钼矿 反萃取 三相物 扩大试验 过滤洗涤

中核集团集中研发项目

中核科发[2021]292号

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(14)