Co-assembly Behavior of Poly oxometalates-Block Copolymer Hybrid Vesicles in Solutions
Poly oxometalates(POMs)are monodisperse nanoclusters with diverse composition and structure.As a new organic and inorganic functional material,polyoxometalates-block copolymer hybrid materials have shown a good application prospect in catalysis,photoelectric chemistry and biochemistry.Here,we propose a simple and novel multi-component co-assembly strategy that combines amphiphilic block copolymer PEO-PS with Keggin-type polyoxomethanate H4SiW through electrostatic interaction.The structures of PEO-PS/H4SiW hybrids were characterized by 1 H NMR,FI-TR and GPC,and their co-assembly behavior was studied by TEM.
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