首页|钠离子电池层状金属氧化物空气稳定性研究

钠离子电池层状金属氧化物空气稳定性研究

扫码查看
近些年来,随着传统化石能源日益匮乏和环境问题日益突出,发展新型清洁能源已成为全球各国的共识。其中,钠离子电池由于其原材料钠在地壳中广泛分布,成本低廉,被认为是未来大规模储能最有前景的储能手段。在众多钠电正极材料中,过渡金属层状氧化物(NaxTMO2)因其具有高的能量密度和锂电三元材料相似的制备工艺、优异的低温性能等优势而备受学术和工业界的关注。目前各界研究重点主要集中在如何抑制钠离子脱/嵌过程中材料结构的转变,循环过程中材料界面保护,提升材料循环性能等问题,对于在实际应用中所面临过渡金属层状氧化物空气稳定性较差的问题研究较少,机理不明确,制约着钠离子电池大规模产业化应用。本文总结了近些年来各界对于该问题的主要研究进展,解决思路,并对钠离子电池未来发展进行了展望。
Research on Air Stability of Layered Metal Oxides for Sodium-ion Batteries
In recent years,as the shortage of traditional fossil fuels has become more apparent and environmental concerns have increased,countries around the world have reached a consensus on the need for new,clean energy sources.Sodium-ion batteries have emerged as one of the most promising technologies for large-scale energy storage,thanks to the wide availability of sodium in the Earth's crust and their relatively low cost.Among the many Na-ion cathode materials,transition metal oxides(NaxTMO2)have drawn significant attention from academia and industry due to their high energy density,similar preparation process to Li-ion cathode materials,and excellent low-temperature performance.However,researchers are currently focused on addressing challenges related to inhibiting material structure transformation during sodium ion removal/intercalation,protecting material interfaces during the cycle process,and improving material cycle performance.While little research has been conducted on the poor air stability of transition metal layered oxide in practical applications,this issue is critical for the large-scale industrial application of sodium-ion batteries.This paper summarizes recent research progress and solutions to this problem,while also offering insights into the future development of sodium-ion batteries.

sodium-ion batterylayered metal oxidescathode materialair stability

徐雅文

展开 >

北京当升材料科技股份有限公司,北京 100160

矿冶科技集团有限公司,北京 100160

钠离子电池 层状金属氧化物 正极材料 空气稳定性

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(14)