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高盐含氟废水处理工艺研究

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针对高盐含氟废水的处理进行了研究,通过实验室及中试放大实验方法完善了处理工艺,优化了指标数据,旨在为实际工业应用提供参考。采用化学沉淀、吸附、高压反渗透及蒸发的联合后处理工艺,废水中的氟以氟化钙的形式从水体中去除,能有效降低废水中氟的含量,氟含量降至1 mg/L以下,废水中超标准的盐采用反渗透系统进行浓缩分离,反渗透产水盐分可以稳定达到1 000 mg/L以下,经过反渗透系统75%的产水进行回收利用。该工艺还通过中试放大验证了工艺和参数的可行性与稳定性,研究结果表明,优化后的处理工艺具有良好的稳定性和可行性,满足国家对氟排放的控制要求,还节约水资源,响应了废水零排放的政策,具有较高的应用价值。
The Study on the Treatment Process of High-Salinity Fluoride-Containing Wastewate
This paper investigates the treatment of high-salinity fluoride-containing wastewater,aiming to provide a reference for practical industrial applications by perfecting the treatment process and optimizing key parameters through laboratory and pilot-scale experiments.The combined post-treatment process employs chemical precipitation,adsorption,high-pressure reverse osmosis,and evaporation.Fluoride in the wastewater is removed as calcium fluoride,effectively reducing fluoride content to below 1 mg/L.The excessive salt in the wastewater is concentrated and separated using a reverse osmosis system,with the salinity of the permeate consistently maintained below 1 000 mg/L.The reverse osmosis system allows for the recovery of 75%of the permeate for reuse.The feasibility and stability of the process and parameters were validated through pilot-scale tests.The results indicate that the optimized treatment process exhibits good stability and feasibility,meets national fluoride discharge standards,conserves water resources,complies with zero liquid discharge policies,and holds significant application value.

high salinity fluoride-containing wastewaterchemical precipitationadsorptionhigh-pressure reverse osmosisprocess optimization

臧正文、于少涛、齐晓巍

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山东百川集大环境工程有限公司,山东济南 250101

高盐含氟废水 化学沉淀 吸附 高压反渗透 工艺优化

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(16)