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灵新煤热解及焦油析出行为研究

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煤热解是煤炭加工利用过程的基础,是气化、液化等加工利用途径的首要步骤。本文通过热重分析法对灵新煤的热失重行为进行分析,发现随着加热速率的升高,热重曲线和微分热重曲线向高温区偏移,产生热滞后现象。搭建了固定床热解实验装置模拟实际生产中热解过程,发现在700 ℃时,煤焦油产率出现最大值,且焦油的产率随着升温速率的增加不断升高。利用分布活化能模型计算了整个热解过程的活化能在44~600 kJ/mol,整个过程的平均活化能为206。43 kJ/mol,且活化能随转化率的增加呈现升高的趋势。该研究可为企业实际生产提供理论依据和参考。
Experimental Investigation on Tar Generation and Pyrolysis of Lingxin Coal
Pyrolysis process is the basis of coal utilization,and the first step of gasification,liquefaction and other process.This article analyzed the influence of temperature and heating rate on LINGXIN coal pyrolysis process.The coal samples was treated with a thermogravimetric analyzer and a fix-bed reactor.The results showed that curves of thermalgracimetric and differential thermogracimetric shifted toward the high temperature region with the increase of heating rate.Fix-bed experimental simulate the actual production process and the results showed that yield of tar increases with the heating rate,while the highest yield of tar was acquired at the temperature of 700 ℃.A general activation energy range of 44~600 kJ/mol was suggested for the pyrolysis process by distributed activation energy model.The activation energy increase as the temperature increases,and the average was 206.43 kJ/mol.This research can provide reference for the actual production.

coal pyrolysisthermogravimetric analysisactivation energytar

冯盛丹、薛新巧

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宁夏工商职业技术学院,宁夏银川 750021

煤热解 热重 活化能 焦油

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(17)