3D Printing Preparation of Thermal-management PVDF/MXene Porous Composite Materials
Radiative heat management is an important research area for passive cooling and heating of objects.However,regulating the unique electromagnetic spectrum reflection and emission properties of materials remains a challenge.To address this issue,PVDF/MXene layered composite porous materials with asymmetric MXene content distribution were fabricated using 3D printing.The cooling side(PVDF side)of the composite exhibited exceptional radiative cooling performance,with high reflectance(98.0%)in the solar band and high emissivity(95.4%)in the atmospheric window.The heating side(MXene side)demonstrated good radiative cooling performance,with low mid-infrared emissivity(18.2%)and high emissivity(70.5%)for solar absorption.Under cooling conditions,the composite porous material achieved a daytime radiative cooling power of 105.8 W·m-2 and an average cooling of 4.1 ℃.Under heating conditions,the heating side of the composite porous material heated up to 9.8 ℃ with an average warming of approximately 5.7 ℃.