山东化工2024,Vol.53Issue(17) :42-49,54.

锂离子电池TiO2-B/Li复合负极的制备及电化学性能研究

Preparation and Electrochemical Performance of TiO2-B/Li Composite Anode for Li-ion Batteries

丁珊修 方苏捷 高洪涛
山东化工2024,Vol.53Issue(17) :42-49,54.

锂离子电池TiO2-B/Li复合负极的制备及电化学性能研究

Preparation and Electrochemical Performance of TiO2-B/Li Composite Anode for Li-ion Batteries

丁珊修 1方苏捷 2高洪涛2
扫码查看

作者信息

  • 1. 青岛碱业发展有限公司,山东青岛 266043
  • 2. 青岛科技大学化学与分子工程学院,山东青岛 266042
  • 折叠

摘要

本文探讨了 TiO2-B/Li复合负极的合成与电化学性质.锂金属和TiO2-B通过机械搅拌和熔融共混两种方法被制备成不同比例的复合负极.通过对半电池的倍率性能和循环稳定性测试,发现熔融共混法制备的质量比为5∶5的Li/TiO2-B复合负极展现出最优异的电化学性能.该复合负极在电池循环过程中未观察到明显的锂枝晶和"死锂"的形成.在3 mA·cm-2和1.5 mAh·cm-2条件下,由m(TiO2-B)∶m(Li)=5∶5复合负极构成的半电池能够稳定地循环1 000圈,且极化电压维持在大约68 mV.此外,还将TiO2-B/Li复合负极与锂离子电池正极材料NCM811和锂硫电池正极材料S@NC配对,构建了全电池,并在1 C和0.5 C的电流密度下进行了循环稳定性测试.TiO2-B/Li-S@NC全电池在0.5 C下循环500圈后,容量保持率为85.37%,容量为640.3 mAh·g-1.同时,TiO2-B/Li-NCM811全电池在1 C下循环500圈后,容量保持率为83.32%.

Abstract

In this study,the synthesis and electrochemical properties of TiO2-B/Li composite anode were investigated.Lithium metal and TiO2-B were prepared into composite anodes with different ratios by both mechanical stirring and melt blending methods.By testing the multiplication performance and cycle stability of the half-cells,we found that the 5∶5 Li/TiO2-B composite anode prepared by the melt blending method exhibited the most excellent electrochemical performance.No obvious lithium dendrites and"dead lithium"formation were observed in this composite anode during the battery cycling.The half-cell composed of m(TiO2-B)∶m(Li)=5∶5 composite anode was able to stably cycle for 1 000 cycles at 3 mA·cm-2 and 1.5 mAh·cm-2,and the polarization voltage was maintained at about 68 mV.In addition,we also paired the TiO2-B/Li composite anode with the lithium-ion battery cathode material,NCM811,and lithium-sulfur battery cathode material,S@NC,and constructed a full-cell,and the full-cell was fabricated at 1.5 mV.The full battery was constructed and tested for cycling stability at current densities of 1 C and 0.5 C.The capacity retention rate was 85.37%and the capacity was 640.3 mAh·g-1 after 500 cycles at 1 C.Meanwhile,the capacity retention rate of the full battery of TiO2-B/Li-NCM811 was 83.32%after 500 cycles at 1 C.

关键词

TiO2-B/Li复合负极/机械混合法/熔融混合法/长循环性能/容量保持率

Key words

TiO2-B/Li composite anode/mechanical mixing method/melt mixing method/long cycle performance/capacity retention rate

引用本文复制引用

出版年

2024
山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
段落导航相关论文