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生物乙醇低温催化产氢研究进展

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生物乙醇水蒸气重整(BESR)反应被认为是一种理想的产氢途径.该方法的产氢效率与催化剂的性质及反应温度密切相关,一般情况下高温可以提升催化剂的产氢效率,但易使催化剂烧结失活,且能耗增加,因此开发低温的高效催化剂是目前研究的重点.本文主要综述了低温催化BESR反应催化剂的研究进展,首先对催化剂的类别进行介绍,分别为单金属负载型催化剂、双金属负载型催化剂和复合类催化剂;然后对影响催化剂活性的因素进行总结归纳,除了活性组分的类别外,载体的性质、活性组分的氧化态以及金属-载体相互作用均对催化剂的活性有显著影响.该综述为系统了解低温催化BESR制氢催化剂提供参考价值.
Research Progress of Catalysts for Hydrogen Production Using Low-temperature Bioethanol Steam Reforming
Bioethanol steam reforming(BESR)reaction is a promissing route of hydrogen production.The hydrogen-efficiency from BESR reaction is closely related with the nature of catalysts and reaction temperature.Usually the high temperature could increase the catalytic activity of catalysts,however it is easy to deactivate the catalyst due to sintering and increase the energy consumption,therefore developing low-temperature and high-efficiency catalysts for BESR reaction is the focus of current research.Herein,the research progress in the studies of the catalysts for BESR reaction at low temperature was reviewed.Firstly,the categories of catalysts,including monometal-supported catalyst,bimetal-supported catalyst and composite catalyst were introduced;secondly,the factors that influenced the activities of the catalysts were summarized,in additon to the type of active compounts,the nature of supports,the chemical state of active catalytic centers and metal-support interatction all had significant effects on the acyivities.The review provides reference value for the systematic understanding of catalysts for BESR at low temperature.

bioethanolhydorgen productionlow temperaturecatalyst

李瑞玲、董高丽、张智然

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黄淮学院化学与制药工程学院,河南驻马店 463000

生物乙醇 产氢 低温 催化剂

2024

山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
年,卷(期):2024.53(17)