山东化工2024,Vol.53Issue(18) :263-265.

生物炭/TiO2光催化复合材料的制备及性能研究

Preparation and Properties of Biochar/TiO2 Photocatalytic Composites

许建刚 贾建岗
山东化工2024,Vol.53Issue(18) :263-265.

生物炭/TiO2光催化复合材料的制备及性能研究

Preparation and Properties of Biochar/TiO2 Photocatalytic Composites

许建刚 1贾建岗1
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作者信息

  • 1. 山西众环创新科技有限公司,山西 太原 030024
  • 折叠

摘要

生物炭具有来源广泛、比表面积大以及表面官能团丰富等优势,将光催化氧化物纳米TiO2 与生物炭复合,是一种具有良好发展前景的光催化复合材料.以松果壳为原料,结合KOH、HCl活化和高温热解制备松果壳多孔生物碳材料,并将其与纳米TiO2 颗粒复合,制备生物碳/TiO2 复合材料.通过扫描电镜(SEM)、比表面积检测(BET)、Raman光谱、紫外-可见分光光度仪对生物碳/TiO2 复合材料进行形貌结构及性能表征.结果表明,所得的生物碳/TiO2 复合材料孔径为 100~200 nm、比表面积为165.36 m2/g,制备的生物碳/TiO2 复合材料对罗丹明B溶液120 min的光降解率达90%以上,为有效处理罗丹明B类有机染料废水提供新材料.

Abstract

Biochar has the advantages of wide source,large specific surface area and abundant surface functional groups.The photocatalytic oxide nano-TiO2 composite with biochar is a promising photocatalytic composite material.The porous biocarbon materials were prepared from pinecone shells by activation of KOH and HCl and pyrolysis at high temperature,and were then combined with nano-TiO2 particles to prepare biocarbon/TiO2 composites.The morphology,structure and properties of biological carbon/TiO2 composites were characterized by scanning electron microscopy(SEM),specific surface area detection(BET),Raman spectroscopy and UV-VIS absorption spectroscopy.The results showed that the pore size of the biocarbon/TiO2 composite was 100~200 nm and the specific surface area was 165.36 m2/g.The photodegradation rate of the biocarbon/TiO2 composite on Rhodamine B solution for 120 min was more than 90%,which provided a new material for the effective treatment of Rhodamine B organic dye wastewater.

关键词

生物炭/光催化/TiO2/染料废水/罗丹明B

Key words

biochar/photocatalysis/TiO2/Dye wastewater/rhodamine B

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出版年

2024
山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
参考文献量4
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