山东化工2024,Vol.53Issue(21) :171-174,182.

皮革制品中19种含氯苯酚的测定

The Determination of 19 Chlorophenol Concentrations in Leather Products

李瑞芳 黄存影 李庆朝 马振宇 张文敏 马德龙 师利龙
山东化工2024,Vol.53Issue(21) :171-174,182.

皮革制品中19种含氯苯酚的测定

The Determination of 19 Chlorophenol Concentrations in Leather Products

李瑞芳 1黄存影 1李庆朝 1马振宇 1张文敏 1马德龙 1师利龙1
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作者信息

  • 1. 国家橡胶助剂工程技术研究中心,山东聊城 252300
  • 折叠

摘要

研究讨论了用气相—气质联用仪测定皮革制品中19种含氯苯酚.本文采用水蒸气蒸馏的方法对样品中的含氯苯酚进行提取,将馏出液收集到含有碳酸钾粉末的锥形瓶中形成溶液,然后用乙酸酐进行乙酰化,再经过正己烷萃取后,用气相—气质联用仪内标法进样检测.本方法的线性关系良好(R2>0.99),重复性良好(0.011%-0.029%),稳定性良好(0.010%~0.032%),精密度良好(0.044%~0.088%),回收率良好(91.2%~98.4%)[1].

Abstract

This article discusses the determination of 19 chlorophenol concentrations in leather products using gas chromatography-mass spectrometry.This article uses the method of steam distillation to extract chlorophenol from the sample.The distillate is collected into a conical flask containing potassium carbonate powder to form a solution,which is then acetylated with acetic anhydride.After being extracted with n-hexane,it is detected by gas chromatography-mass spectrometry and internal standard injection method.This method has good linear relationship(R2>0.99),good repeatability(0.011%~0.029%),good stability(0.010%~0.032%),good precision(0.044%~0.088%),and good recovery rate(91.2%~98.4%).

关键词

含氯苯酚/蒸汽蒸馏/乙酰化/气相—气质联用

Key words

chlorophenol/steam distillation/acetylation/gas chromatography-mass spectrometry

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出版年

2024
山东化工
山东省化工研究院 山东省化工信息中心

山东化工

影响因子:0.249
ISSN:1008-021X
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