首页|三元乙丙橡胶密封垫长期防水性能预测研究

三元乙丙橡胶密封垫长期防水性能预测研究

Prediction of Long-Term Waterproof Performance of Ethylene Propylene Diene Monomer Sealing Gasket

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为对盾构隧道密封垫长期防水性能进行预测,通过总结以往的密封垫性能预测方法与老化试验方法及成果,参考以往研究将老化试验温度控制在 90℃以内、老化时长控制在 168 h以内,开展哑铃Ⅰ型三元乙丙橡胶(ethylene propylene diene monomer,EPDM)热氧老化试验,分析EPDM 试件拉断伸长率、拉伸强度和拉断永久变形率的变化规律,给出化学层面的解析,并与以往EPDM密封垫老化试验结果进行对比.根据试验结果认为:EPDM拉断伸长率和拉断永久变形率的衰减是EPDM密封垫防水能力下降的原因之一,EPDM拉伸强度对EPDM密封垫防水能力影响较小,采用EPDM单个拉伸性能指标老化规律预测密封垫长期防水能力不可靠.最后,基于阿伦尼乌斯方程的动力学曲线直化法,预测EPDM拉断伸长率 100 年后的老化系数约为 37%.
To explore the prediction method for long-term waterproof performance of sealing gaskets,the previous methods for predicting and fitting the performance of sealing gaskets in shield tunnels,as well as the aging test methods and results are summarized.On the basis of previous research,the aging test temperature is controlled within 90℃and the aging duration is controlled within 168 h.The thermal oxygen aging test of dumbbell type I ethylene propylene diene monomer(EPDM)is conducted,the variation patterns of the elongation at break,tensile strength,and permanent deformation rate at break of EPDM are analyzed,and a chemical analysis is provided.According to the experimental results,the attenuation of EPDM elongation at break and permanent deformation at break is one of the reasons for the decrease in the waterproof performance of EPDM sealing gaskets.The tensile strength of EPDM has a small impact on the waterproof performance of EPDM sealing gaskets,and predicting the long-term waterproof performance of sealing gaskets using a certain index's attenuation pattern is not reliable.The kinetic curve straightness method based on the Arrhenius equation predicts that the attenuation coefficient of EPDM elongation at break after 100 years is 37%.

shield tunnelethylene propylene diene monomer sealing gasketthermal oxygen agingwaterproof performance

李睿佳、汪元冶、龚琛杰、王帆、丁文其

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同济大学土木工程学院地下建筑与工程系,上海 200092

中南大学土木工程学院,湖南 长沙 410075

南京大学化学化工学院,江苏 南京 210023

盾构隧道 三元乙丙橡胶密封垫 热氧老化 防水性能

国家自然科学基金国家自然科学基金

5209008352378405

2024

隧道建设(中英文)
中铁隧道集团有限公司洛阳科学技术研究所

隧道建设(中英文)

CSTPCD北大核心
影响因子:0.785
ISSN:2096-4498
年,卷(期):2024.44(z1)
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