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等离激元纳腔的构建及其在表面增强拉曼散射中的应用

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表面增强拉曼光谱(SERS)技术由于其高灵敏度、指纹特性和非破坏性等特点,在各领域引起了广泛的关注和应用。金属纳米结构形成的纳米尺寸的间隙(纳腔)作为SERS技术的重要组成部分,其形貌、组成和间距决定了 SERS光谱的灵敏性和稳定性。因此,构建高质量的等离激元纳腔备受关注。本文旨在综述纳腔的构建方法及其在SERS中的应用。首先,介绍SERS增强的基本原理;其次,分类讨论制备高灵敏、可调控及均匀纳腔的方法,包括疏水衬底自收缩法、两步光还原法、模板法、自组装法和应变诱导开裂法等;再次,介绍SERS技术在食品安全、环境卫生以及生物医学等领域中的应用;最后,对SERS技术的前景进行展望,指出其在不同领域中的潜在应用价值和挑战。
Construction of plasmonic nanocavity and their application in surface-enhanced Raman scattering
Surface-enhanced Raman scattering(SERS)technology has attracted significant attention and applications in various fields due to its high sensitivity,fingerprinting properties and non-destructive properties.Metal nanostructures form nano-sized gaps(nanocavity)as an important part of the SERS technique,and their morphology,composition and spacing determine the sensitivity and stability of SERS spectra.Therefore,the construction of high-quality plasmonic nanocavity has attracted much attention.The aim of this paper is to review the construction methods of nanocavity and the applications in SERS.Firstly,it introduces the principles of SERS enhancement.Secondly,the methods of preparing highly sensitive,tunable and uniform nanocavity are classified and discussed,including hydrophobic substrate self-shrinkage,two-step photo-reduction,template,self-assembly,and strain-induced cracking,etc.Thirdly,the applications of SERS technology in the fields of food safety,environmental health,and biomedicine are introduced.Finally,the future prospect of SERS technology is outlooked,pointing out the potential value of its applications and challenges in different fields.

surface-enhanced Raman scatteringplasmonic nanocavityenhancement factor

张萌、周怡汐、李志鹏

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首都师范大学物理系,北京 100048

表面增强拉曼散射 等离激元纳腔 增强因子

国家自然科学基金项目国家重点研发计划项目北京市自然科学基金项目国家青年人才支持计划项目北京市自然科学基金重点研究专题项目

123740282021YFA1400800Z190006Z240005

2024

首都师范大学学报(自然科学版)
首都师范大学

首都师范大学学报(自然科学版)

CSTPCD
影响因子:0.537
ISSN:1004-9398
年,卷(期):2024.45(2)