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再生催化裂化催化剂结构及性能

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采用固定床装置制备了 2种碳质量分数分别为0.25%,0.04%的再生催化裂化催化剂,利用X射线衍射仪、物理吸附仪、扫描电子显微镜等对催化剂进行表征,考察了再生过程对催化剂结构的影响,并对再生催化剂的性能进行评价.结果表明:再生过程不会影响催化剂中分子筛结构;催化剂失活的主要原因是焦炭堵塞孔道,覆盖了弱酸性活性位点,再生过程除去焦炭后,催化剂活性得到恢复;催化剂碳质量分数越低,原料油转化率越高,热裂化指数越低;再生催化剂上原料油转化率最高可达83.68%,热裂化指数仅为 0.19.
Structure and performance of regenerated fluid catalytic cracking catalysts
Two kinds of regenerated fluid catalytic cracking catalysts with carbon mass fraction of 0.25%and 0.04%were prepared by using a fixed bed de-vice.The catalysts were characterized by X-ray diffractometer,N2 adsorption,scanning electron mi-croscope.The influence of the regeneration process on catalyst structure and the performance of regener-ated catalysts were studied.The results showed that the regeneration process didn't affect the molecular sieve structure in the catalyst;the main reason for catalyst deactivation was that coke blocked the pores and covered the weak acidic active sites.The regen-eration process removed the coke and the catalyst activity was restored;the lower the carbon mass fraction of the catalyst,the higher the feed oil con-version rate,the lower the thermal cracking index;the feed oil conversion rate on the regenerated cata-lyst could reach up to 83.68%,and the thermal cracking index was only 0.19.

fluid catalytic crackingcatalystre-generationcokethermal cracking index

潘志爽、熊晓云、蔡进军、吴文尧、何涛

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中国石油石油化工研究院兰州化工研究中心,甘肃兰州 730060

中国石油兰州石化公司催化剂事业部,甘肃兰州 730060

中国石油云南石化有限公司 生产一部,云南 昆明 650399

催化裂化 催化剂 再生 焦炭 热裂化指数

中国石油天然气股份有限公司科技管理部资助项目

2018 E-03-01

2024

石化技术与应用
兰州石化公司石油化工研究院

石化技术与应用

CSTPCD
影响因子:0.491
ISSN:1009-0045
年,卷(期):2024.42(1)
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