石化技术与应用2024,Vol.42Issue(2) :83-87.DOI:10.19909/j.cnki.ISSN1009-0045.2024.02.0083

NaY分子筛复合材料及其催化裂化催化剂性能

NaY molecular sieve composite material and its fluid catalytic cracking catalyst performance

胡清勋 谢恒 姜燕 童加强 刘宏海
石化技术与应用2024,Vol.42Issue(2) :83-87.DOI:10.19909/j.cnki.ISSN1009-0045.2024.02.0083

NaY分子筛复合材料及其催化裂化催化剂性能

NaY molecular sieve composite material and its fluid catalytic cracking catalyst performance

胡清勋 1谢恒 2姜燕 1童加强 3刘宏海1
扫码查看

作者信息

  • 1. 中国石油石油化工研究院 兰州化工研究中心,甘肃 兰州 730060
  • 2. 中国石油兰州石化公司,甘肃 兰州 730060
  • 3. 中国石油庆阳石化公司 炼油一部,甘肃 庆阳 745000
  • 折叠

摘要

以高岭土和水玻璃为原料,采用水热法原位晶化合成了NaY分子筛复合材料,通过离子交换法改性并制备出催化裂化催化剂,利用X射线荧光仪、N2 吸附-脱附仪、扫描电子显微镜等仪器对试样进行结构表征,在固定流化床微型反应器装置上进行催化剂裂化反应性能评价.结果表明:该NaY分子筛复合材料的外比表面积为 93.70 m2/g,介孔孔容为 0.19 cm3/g,颗粒直径约在 300~500 nm;改性后复合材料的介孔主要分布在 2~20 nm,且为双孔分布,分布峰分别为 3.8,5.6 nm;与常规NaY型分子筛催化剂相比,采用该NaY型分子筛复合材料所制备的催化剂其反应转化率、液化气和总液体收率依次提高 6.18,5.16,1.61个百分点,重油收率下降 3.34 个百分点,生焦因子下降 0.80.

Abstract

NaY molecular sieve composite mate-rial was in-situ synthesized by kaolin and water glass using hydrothermal method,the fluid catalytic cracking catalyst was prepared by NaY molecular sieve composite material modified through ion ex-change method.The structure of the samples was characterized by X-ray fluorescence,N2 adsorption desorption,scanning electron microscopy,and oth-er instruments.The catalytic cracking reaction per-formance was evaluated on a fixed fluidized bed mi-cro reactor device.The results indicated that the external specific surface area of the NaY molecular sieve composite material was 93.70 m2/g,the meso-porous pore volume was 0.19 cm3/g,and the parti-cle diameter was about 300-500 nm.The mesopores of the modified composite material were mainly dis-tributed in the range of 2-20 nm and exhibited a bimodal pore distribution,with distribution peaks of 3.8 and 5.6 nm respectively.Compared with con-ventional NaY-type molecular sieve catalysts,the conversion rate,liquefied gas and total liquid yield of catalyst prepared by this NaY-type molecular sieve composite material increased by 6.18,5.16,and 1.61 percentage points respectively,while the heavy oil yield decreased by 3.34 percentage points and the coking factor decreased by 0.80.

关键词

催化裂化催化剂/NaY分子筛复合材料/高岭土/介孔

Key words

fluid catalytic cracking catalyst/NaY molecular sieve composite material/kaolin/mesopore

引用本文复制引用

基金项目

中国石油项目(2020A-1818)

出版年

2024
石化技术与应用
兰州石化公司石油化工研究院

石化技术与应用

CSTPCD
影响因子:0.491
ISSN:1009-0045
参考文献量9
段落导航相关论文