首页|基于Aspen Plus软件的双酚A装置反应单元流程模拟与优化

基于Aspen Plus软件的双酚A装置反应单元流程模拟与优化

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利用Aspen Plus流程模拟软件对离子交换树脂法合成双酚A装置反应单元工艺进行了建模,考察了反应单元进料温度、苯酚/丙酮质量比、丙酮至一段反应器比例等参数对丙酮转化率、双酚A收率及其选择性的影响,并对操作参数进行了优化.结果表明:在单因素变化情况下,反应单元进料温度升高,或苯酚/丙酮质量比降低,或丙酮至一段反应器比例增大,均会使双酚A收率和丙酮转化率增大;在一段、二段反应器进料温度分别为 65,76℃,苯酚/丙酮质量比为 15.0,丙酮至一段反应器比例为 1.00 的优化条件下,双酚A收率、丙酮转化率分别提高 3.96,4.30 个百分点.
Process simulation and optimization of reaction unit in bisphenol A plant based on Aspen Plus software
A simulation model for the reaction unit of synthesis of bisphenol A plant by ion exchange resin was built by Aspen Plus process simulation software.The feed temperature,the mass ratio of phenol/acetone and the ratio of acetone to the first stage reactor were investigated.The effects of main operation conditions on conversion rate of acetone,yield of bisphenol A and selectivity were analyzed and optimized.The results showed that the yield of bisphenol A and the conversion rate of acetone in-creased with the increase of feed temperature,the decrease of mass ratio of phenol/acetone,or the in-crease of the proportion of acetone to the first stage reactor under the case of single factor variation.Un-der the optimized conditions of the first and second stage reactors feed temperature of 65,76℃,mass ratio of phenol/acetone of 15.0,and mass ratio of acetone to the first stage reactor of 1.00,the yield of bisphenol A and conversion rate of acetone could be increased by 3.96 and 4.30 percentage points,re-spectively.

bisphenol A plantprocess simula-tionAspen Plus softwarereaction unitphenolace-toneconversion rateyield

李得伦、童朝忠、刘亭亭、姚鑫、刘旭明、冯恩波、李琬菁、毛玲娟

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浙江石油化工有限公司,浙江 舟山 316000

浙江省绿色石化技术创新中心,浙江 宁波 315048

中国寰球工程有限公司,北京 100012

华东理工大学 信息科学与工程学院,上海 200237

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双酚A装置 流程模拟 Aspen Plus软件 反应单元 苯酚 丙酮 转化率 收率

浙江省重点科技开发资助项目浙江石油化工有限公司科学研究与技术开发项目

2020C01010ZSH-RD-22-088

2024

石化技术与应用
兰州石化公司石油化工研究院

石化技术与应用

CSTPCD
影响因子:0.491
ISSN:1009-0045
年,卷(期):2024.42(2)
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