首页|中压加氢裂化装置生产5号工业白油的工艺改进

中压加氢裂化装置生产5号工业白油的工艺改进

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在中国石化洛阳分公司 150 万t/a蜡油中压加氢裂化装置中,分别采用减压轻蜡油、直馏柴油、催化柴油组成的混合原料(蜡油进料模式)和直馏柴油、催化柴油、渣油加氢柴油组成的混合原料(柴油进料模式)进行了 5号工业白油的生产,通过工艺改进,解决了产品运动黏度不达标的问题.结果表明:在柴油进料模式下,将循环氢流量由 195717 m3/h提高至 214780 m3/h,反应系统压力由 8.7 MPa提高至 10.2 MPa,精制(裂化)反应器入口温度由 300(321)℃升高至 318(352)℃,加氢裂化尾油产品的运动黏度降低至 5.008 mm2/s;将分馏塔汽提介质由蒸汽改为氮气,可解决尾油带水的问题;将尾油部分外甩至催化装置或罐区,以解决易着色物质在尾油中富集的问题;在蜡油原料模式下,将航空煤油抽出量由 30 t/h提高至 45 t/h,柴油抽出量由 63 t/h降低至 55 t/h,柴油侧线产品的闪点和运动黏度分别增加至 132℃,4.361 mm2/s,达到白油指标要求.
Process improvement of producing 5# industrial white oil in medium pressure hydrocracking unit
The 5# industrial white oil was produced by using the mixed raw materials composed of vacu-um light wax oil,straight-run diesel and catalytic diesel(wax oil feeding mode)and the mixed raw materials composed of straight-run diesel,catalytic diesel and residual hydrodiesel oil(diesel feeding mode)in the 1.5 Mt/a wax oil medium pressure hy-drocracking unit of Luoyang Petrochemical Compa-ny of SINOPEC.The problem that the kinematic viscosity of the product was not up to standard was solved.The results showed that the circulating hy-drogen flow rate was increased from 195 717 m3/h to 214 780 m3/h,the reaction system pressure was in-creased from 8.7 MPa to 10.2 MPa,and the inlet temperature of the refining(cracking)reactor was increased from 300(321)℃to 318(352)℃in the diesel feeding mode.The kinematic viscosity of the hydrocracking tail oil product was reduced to 5.008 mm2/s.The problem of water in tail oil could be solved by changing the stripping medium of frac-tionator from steam to nitrogen.The tail oil part was thrown out to the catalytic unit or tank field to solve the problem of enrichment of easily colored sub-stances in the tail oil.The extraction amount of avi-ation kerosene was increased from 30 t/h to 45 t/h,the extraction amount of diesel was reduced from 63 t/h to 55 t/h,and the flash point and kinematic viscosity of diesel line products were increased to 132℃,4.361 mm2/s,which met the requirements of white oil indicators in the wax oil feeding mode.

medium pressure hydrocracking5#industrial white oildieselwax oilhydrocracking tail oilkinematic viscosity

任研研、武林希彦、翟志清、杨新梅、陈正杰

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中国石化洛阳分公司 技术质量部,河南 洛阳 471000

中国石化宁波工程有限公司 建设安装分公司,浙江 宁波 315103

乌鲁木齐市检验检测中心(乌鲁木齐市粮油质量监测站),新疆 乌鲁木齐 830000

中压加氢裂化 5 号工业白油 柴油 蜡油 加氢裂化尾油 运动黏度

2024

石化技术与应用
兰州石化公司石油化工研究院

石化技术与应用

CSTPCD
影响因子:0.491
ISSN:1009-0045
年,卷(期):2024.42(2)
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