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二氧化碳加氢制甲醇Cu基催化剂疏水改性研究进展

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综述Cu基催化剂研究现状和二氧化碳加氢制甲醇的反应机理,分析在二氧化碳反应过程中水对催化剂的影响,从催化剂组分、微观结构以及反应装置设计等方面阐述Cu基催化剂耐水热稳定性的改性技术,并指出优化制备工艺、调控反应工艺、开发疏水改性技术、开发新型反应器等是解决Cu基催化剂失活的改进方向.
Research progress on hydrophobic modification of Cu-based catalysts for hydrogenation of carbon dioxide to methanol
The research status of Cu-based cata-lysts and the reaction mechanism of carbon dioxide hydrogenation to methanol were reviewed with 50 references.The effect of water on catalysts during carbon dioxide reaction was analyzed,and the modi-fication technology of Cu-based catalysts for hy-drothermal stability was elaborated in terms of the design of catalyst components,the design of mi-crostructures,and the design of the reaction device.It was also pointed out that the optimization of the preparation process,and the regulation of the reac-tion process,and the development of hydrophobic modification technology,and the development of new types of reactor were the directions of improvement for the solution of the deactivation of Cu-based cata-lysts.

Cu-based catalystmethanolcarbon dioxide hydrogenationhydrophobic modificationhydrothermal stability

何琴、李中付、王群斐、张景岩、刘从华

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山东理工大学 材料科学与工程学院,山东 淄博 255000

山东省高校稀土催化新材料工程研究中心,山东 淄博 255000

Cu基催化剂 甲醇 二氧化碳加氢 疏水改性 水热稳定性

淄博市重点研发校城融合项目

2021SNPT0042

2024

石化技术与应用
兰州石化公司石油化工研究院

石化技术与应用

CSTPCD
影响因子:0.491
ISSN:1009-0045
年,卷(期):2024.42(2)
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