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石墨烯负载ZnO光催化剂制备及其降解染料废水性能

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采用溶胶-凝胶法制备出一系列石墨烯(GE)负载ZnO光催化剂,利用X射线衍射仪和紫外-可见漫反射光谱仪等仪器对合成的催化剂进行表征,考察了光源、ZnO/GE质量比、光催化剂用量以及染料废水质量浓度对催化剂性能的影响.结果表明:ZnO在GE上晶面生长完整,结晶度良好;GE提高了 ZnO的光量子利用率;在紫外光,ZnO/GE质量比为0.5,催化剂用量(占反应体系的质量分数)为4%,染料废水质量浓度为15mg/L的最优条件下,染料降解率高达84%.
Preparation of graphene-supported ZnO photocatalyst and its performance in degradation of dye wastewater
A series of graphene(GE)supported ZnO photocatalysts were prepared by sol-gel method.The synthesized catalysts were characterized by X-ray diffractometer and ultraviolet-visible diffuse re-flectance spectrometer.The effects of light source,ZnO/GE mass ratio,photocatalyst dosage and dye wastewater concentration on the performance of the catalysts were investigated.The results showed that the growth of ZnO on the crystal surface of GE was complete and the crystallinity of the catalysts was good.The use of GE increased the photoquantum ef-ficiency of ZnO.Under the optimal conditions of ul-traviolet light,ZnO/GE mass ratio of 0.5,catalyst dosage(mass fraction of the reaction system)of 4%,and dye wastewater concentration of 15 mg/L,the dye degradation rate was as high as 84%.

sol-gelgraphenezinc oxidephoto-catalystdye wastewaterdegradation

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重庆市南岸区生态环境监测站,重庆 404100

溶胶-凝胶 石墨烯 氧化锌 光催化剂 染料废水 降解

重庆市科技局项目

2008 ZX07315-005

2024

石化技术与应用
兰州石化公司石油化工研究院

石化技术与应用

CSTPCD
影响因子:0.491
ISSN:1009-0045
年,卷(期):2024.42(3)