首页|锂离子电池隔膜专用聚丙烯T98系列产品的性能及其应用

锂离子电池隔膜专用聚丙烯T98系列产品的性能及其应用

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为满足国内锂离子电池隔膜专用料的市场需求,中国石油独山子石化公司采用Spheripol双环管工艺生产出锂离子电池隔膜专用聚丙烯(PP)T 98 系列产品,剖析了T 98 G/T 98 F/T 98 D/T 98 CD等产品的基础性能、力学性能、热性能、相对分子质量及其分布以及隔膜制品性能.结果表明:与进口典型对标试样相比,T 98 系列产品的氧化诱导时间(约 38 min)较长,数均分子质量(约 12.0×104)更大,相对分子质量分布(约 3.1)更窄;T 98 F/T 98 G适用于干法双向拉伸工艺,T 98 D/T 98 CD适用于干法单向拉伸工艺;与进口试样制品相比,T 98 D/T 98 CD生产的锂离子电池隔膜制品透气层间极差分别降低 8.8%,19.8%,纵向拉伸强度分别提高 11.6%,25.4%,隔膜孔径集中度好、分布均匀、无明显双峰.
Performance and application of special polypropylene T 98 series products for lithium ion battery separator
In order to meet the domestic market de-mand for special materials for lithium ion battery separator,special polypropylene(PP)T 98 series products for lithium ion battery separator was pro-duced by using Spheripol double ring tube process by Dushanzi Petrochemical Company of PetroChina.The basic properties,mechanical properties,ther-mal properties,relative molecular weight and its distribution of T 98 G/T 98 F/T 98 D/T 98 CD and the properties of diaphragm products were analyzed.The results showed that compared with typical im-ported benchmark samples,the oxidation induced time of T 98 series products(about 38 min)was longer,the number average molecular weight(about 12.0×104)was larger,and the relative molecular weight distribution(about 3.1)was narrower.T 98 F/T 98 G was suitable for dry biaxial drawing process and T 98 D/T 98 CD was suitable for dry uniaxial drawing process.Compared with imported sample products,the range between the breathable layers of the lithium ion battery separator products produced by T 98 D/T 98 CD decreased by 8.8%and 19.8%respectively,and the longitudinal tensile strength increased by 11.6%and 25.4%respectively.The separator pore size concentration was good,the dis-tribution was uniform,and no obvious double peaks.

polypropylenelithium ion battery separatormelt flow rateoxidation induced timetensile strength

谌基国、张工厂、张彪、崔晓伟、谷新华

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中国石油独山子石化公司研究院,新疆 克拉玛依 833699

新疆橡塑材料实验室,新疆 克拉玛依 833699

中国石油独山子石化公司工程管理部,新疆 克拉玛依 833699

中国石油独山子石化公司规划和科技信息部,新疆 克拉玛依 833699

中国石油独山子石化公司聚烯烃二部,新疆 克拉玛依 833699

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聚丙烯 锂离子电池隔膜 熔体流动速率 氧化诱导时间 拉伸强度

中国石油独山子石化公司资助项目

DSH16-04

2024

石化技术与应用
兰州石化公司石油化工研究院

石化技术与应用

CSTPCD
影响因子:0.491
ISSN:1009-0045
年,卷(期):2024.42(5)
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