石化技术与应用2024,Vol.42Issue(5) :389-394.DOI:10.19909/j.cnki.ISSN1009-0045.2024.05.0389

CH4-CO2干重整Ni基催化剂性能调控及应用技术研究进展

Research progress on performance regulation and application technology of Ni-based catalysts for CH4-CO2 dry reforming

王连英 李洪宝 辛靖 杨国明 宋宇 陈禹霏
石化技术与应用2024,Vol.42Issue(5) :389-394.DOI:10.19909/j.cnki.ISSN1009-0045.2024.05.0389

CH4-CO2干重整Ni基催化剂性能调控及应用技术研究进展

Research progress on performance regulation and application technology of Ni-based catalysts for CH4-CO2 dry reforming

王连英 1李洪宝 1辛靖 1杨国明 1宋宇 1陈禹霏1
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作者信息

  • 1. 中海石油化工与新材料科学研究院,北京 102209
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摘要

基于CH4-CO2 干重整(DRM)反应的热力学和反应机理,从Ni颗粒尺寸、空间限域结构、形成氧空位和增加活性氧物种等方面综述了避免Ni基催化剂积炭和烧结的调控技术,以及等离子体-催化剂耦合和光热协同催化DRM的应用技术,展望了DRM技术的发展方向.指出利用可再生电能协同发展等离子体以及光热催化DRM技术具有良好的发展前景.

Abstract

Based on the thermodynamics and reac-tion mechanism of CH4-CO2 dry reforming(DRM)reaction,the control technologies to avoid Ni based catalyst coking and sintering,as well as the applica-tion technologies of plasma catalyst coupling and photothermal synergistic catalysis for DRM were summarized with 31 references from the aspects of Ni particle size,spatial confinement structure,forma-tion of oxygen vacancies,and increase of active oxy-gen species.The development direction of DRM technology was prospected.It was pointed out that the use of renewable electricity to synergistically de-velop plasma and photothermal catalysis for DRM technology had good development prospects.

关键词

CH4-CO2干重整/Ni基催化剂/积炭/烧结/等离子体/光热催化

Key words

CH4-CO2 dry reforming/Ni-based catalyst/carbon deposition/sintering/plasma/pho-tothermal catalysis

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基金项目

中国海洋石油集团公司科技资助项目(KJGG-2022-12CCUS3-4-2)

出版年

2024
石化技术与应用
兰州石化公司石油化工研究院

石化技术与应用

CSTPCD
影响因子:0.491
ISSN:1009-0045
参考文献量6
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