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高性能抗紫外阻燃增强PBT材料的制备及性能研究

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通过双螺杆挤出机熔融共混,制备了溴化环氧与三氧化二锑复配的耐户外用阻燃聚对苯二甲酸丁二醇酯(PBT)工程塑料,考察了不同溴系阻燃剂对PBT工程塑料力学性能、阻燃性能、抗紫外(UV)性能的影响,抗氧剂种类及抗UV剂添加量对PBT工程塑料抗UV性能的影响.结果表明:溴系阻燃剂选用溴化环氧且添加量(质量份数,下同)为12 份时,材料的力学性能、阻燃性能与抗UV性能达到最佳,辅抗氧剂选用626,主抗氧剂选用1010,抗UV剂添加量为0.4 份时,PBT工程塑料抗UV性能达到最佳,制得的PBT工程塑具有较好的综合力学性能(拉伸、弯曲强度分别为 150 MPa、210 MPa,缺口和无缺口冲击强度分别为 12.0 kJ/m2、65.0 kJ/m2)、抗UV性能及阻燃性能,其阻燃等级达 UL 94 V-0 级(0.8 mm).
Study on the Preparation and Properties of High Performance Anti UV Flame Retardant Reinforced PBT Materials
Flame retardant polybutylene terephthalate(PBT)engineering plastic for outdoor use was prepared by melt blending of brominated epoxy and antimony trioxide by twin-screw extruder.The effects of different brominated flame re-tardants on the mechanical properties,flame retardancy and UV resistance of PBT engineering plastics were investigated,as well as the effects of antioxidant types and anti-UV additive amount on anti-UV properties of PBT engineering plastics.The results show that the mechanical properties,flame retardant properties and UV resistance of PBT engineering plastics reach the best when brominated epoxy is selected as the flame retardant and the addition amount is 12 parts.The UV re-sistance of PBT engineering plastics reaches the best when 626 is selected as the auxiliary antioxidant,1010 is selected as the main antioxidants,and the addition amount of anti UV agent is 0.4 parts.The PBT engineering plastic has good comprehensive mechanical properties(tensile and bending strengths are 150 MPa and 210 MPa,notched and unnotched impact strengths are 12.0 kJ/m2 and 65.0 kJ/m2,respectively),UV resistance and flame retardant properties,and its flame retardant grade is UL 94 V-0(0.8 mm).

polybutylene terephthalateflame retardantUV resistantengineering plastic

翁书元、贾义军、陈国军、唐治中、马清云

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宁波华腾首研新材料有限公司,浙江宁波 315400

北京市化学工业研究院有限责任公司,北京 100084

聚对苯二甲酸丁二醇酯 阻燃 抗紫外 工程塑料

2024

上海塑料
上海塑料工程技术学会 上海市塑料制品工业研究所

上海塑料

影响因子:0.134
ISSN:1009-5993
年,卷(期):2024.52(1)