首页|三塘湖盆地中二叠统芦草沟组油页岩热重特性及影响因素

三塘湖盆地中二叠统芦草沟组油页岩热重特性及影响因素

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为了研究油页岩加热过程中的热重特性和热解过程及其影响因素,对三塘湖盆地芦草沟组油页岩的含油率、总有机碳、热解、主量元素和热重分析等进行测试.结果显示,三塘湖盆地芦草沟组油页岩为具有较高有机质丰度、高灰分和中等发热量的中等品质油页岩,且灰分主要元素组成为SiO2、Al2O3、CaO,属于高熔灰分.油页岩热重分析显示其热解过程主要为低温、中温和高温失重段3个阶段,中温失重段为油页岩主要失重段和油页岩热解反应阶段,温度范围为300~580 ℃.其中油页岩热解过程中油气大量生成阶段的温度范围为430~500℃,为油页岩热解过程中生油关键阶段,而500~580 ℃为页岩气生成阶段,可以形成一定量的页岩气.
Thermogravimetric characteristics and its influencing factors of oil shales in Middle Permian Lucaogou Formation in Santanghu Basin,NW China
In order to study the thermogravimetric characteristics,pyrolysis process and its influencing factors of oil shales during heating,the oil yield,total organic carbon,pyrolysis,major elements and thermogravimetric analysis of oil shales from the Lucaogou Formation in Santanghu Basin were tested.The results show that oil shales from the Lucaogou Formation in Santanghu Basin are medium quality oil shales with high organic matter abun-dances,high ash contents and medium calorific values.The main elements of ashes are SiO2,Al2O3 and CaO,which belong to high melting ashes.Thermogravimetric analysis of oil shale shows that the pyrolysis process is mainly divided into three stages,including low temperature,medium temperature and high temperature weight loss stages.The medium temperature weight loss stage is the main weight loss stage and pyrolysis reaction stage of oil shales,with the temperature of 300-580 ℃.Among them,the temperature of large amount of oil and gas genera-tion stage in oil shale pyrolysis process is 430-500 ℃,which is the key stage of oil generation.While 500-580 ℃ is the gas generation stage,which can form a certain amount of shale gas.

oil shalethermogravimetric analysispyrolysisLucaogou FormationSantanghu Basin

陈贵标、徐银波

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中国电建集团昆明勘测设计研究院有限公司,昆明 650051

中国地质调查局油气资源调查中心,北京 100083

吉林大学地球科学学院,长春 130061

油页岩 热重分析 热解 芦草沟组 三塘湖盆地

中国地质调查局项目中国地质调查局项目国家自然科学基金项目国家自然科学基金项目

DD20230325DD202425094177209252374010

2024

世界地质
吉林大学 东北亚国际地学研究与教学中心

世界地质

CSTPCD
影响因子:0.769
ISSN:1004-5589
年,卷(期):2024.43(3)