首页|MPOP/TPP/PER复合阻燃剂对PP燃烧行为的影响

MPOP/TPP/PER复合阻燃剂对PP燃烧行为的影响

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采用熔融共混法制备了聚丙烯/三聚氰胺聚磷酸盐/磷酸三苯酯(PP/MPOP/TPP)和聚丙烯/三聚氰胺聚磷酸盐/磷酸三苯酯/季戊四醇(PP/MPOP/TPP/PER)复合材料,研究了不同阻燃组分配比对PP燃烧行为的影响.结果表明:当MPOP/TPP复合阻燃剂的添加量为30份、MPOP与TPP的质量比为20/10时,PP/MPOP/TPP复合材料的热稳定性下降,但其阻燃性能有一定程度的提高.在该体系中添加7.5份PER,当复合阻燃剂FR(MPOP/TPP=20/10)与PER的配比为22.5/7.5时,材料的热稳定性下降,但成炭效果增加,极限氧指数(LOI)达到22.6%,较纯PP提高了26.97%;同时材料的热释放速率、总释热量,有效燃烧热和有害气体的产率均明显减小,PP/MPOP/TPP/PER阻燃复合材料的阻燃性能显著提高.
Effect of MPOP/TPP/PER Composite Flame-retardant on Burning Behavior of PP
Polypropylene/melamine polyphosphate/triphenyl phosphate (PP/MPOP/TPP) composites and PP/MPOP/TPP/pentaerythritol (PER) composites were prepared by the method of melt-blending.The effect of mass ratio of different flame-retardant components on the burning behavior of PP was also studied.The results show that,when the content of flame retardant is fixed at 30% of pure PP,and the mass ratio of MPOP and TPP is 20/10,the thermal stability of the composites decreases,while its flame-retardant property increases.Adding PER to the above system,when the total content of FR,in which the mass ratio of MPOP and TPP is 20/10,and PER is 22.5/7.5,the thermal stability of the materials decreases,but the effect of coal-forming increases,the limited oxygen index (LOI) reaches to 22.6%,increased by 26.97% than that of pure PP,the rate of heat release,the total heat release,the effective heat of combustion and the productivity of harmful gas all decrease obviously.The flame-retardant property of PP/MPOP/TPP/PER composites improves obviously.

PPMPOPTPPPERCompositeThermal stabilityFlame-retardant property

杨成志、程利萍、刁梦娜、邱学剑、田瑶珠、秦军

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贵州大学材料与冶金学院,贵州贵阳550003

贵州大学喀斯特环境与地质灾害防治教育部重点实验室,贵州贵阳550003

聚丙烯 三聚氰胺聚磷酸盐 磷酸三苯酯 季戊四醇 复合材料 热稳定性 阻燃性能

黔科合重大专项字

20116023

2014

塑料科技
大连塑料研究所有限公司 深圳市塑胶行业协会

塑料科技

CSTPCD北大核心
影响因子:0.553
ISSN:1005-3360
年,卷(期):2014.42(1)
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