首页|无规共聚聚丙烯管材耐聚氨酯防水涂料腐蚀性的研究

无规共聚聚丙烯管材耐聚氨酯防水涂料腐蚀性的研究

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研究了无规共聚聚丙烯管(PPR管)在不同条件下与聚氨酯防水涂料、二甲苯稀释剂接触后的变化,测定PPR管的拉伸性能和热学性能,探讨聚氨酯防水涂料、二甲苯稀释剂对PPR管性能的影响.结果表明:聚氨酯防水涂料中小分子有机物和二甲苯稀释剂均渗透到PPR管中,降低PPR管的屈服强度和断裂伸长率.聚氨酯防水涂料中小分子有机物渗入PPR管分子链的空隙中,增大了分子链段间的体积,二甲苯稀释剂加快聚氨酯防水涂料中小分子有机物的渗透,PPR管溶胀更明显,力学强度损失增大.小分子有机物对PPR管的抗氧化性有不良影响.聚氨酯防水涂料与PPR直接接触时,聚氨酯防水涂料中小分子有机物会渗透到PPR管中,影响PPR管的力学性能和抗氧化性等性能.
Study on Corrosion Resistance of Polyurethane Waterproof Coatings for Random Copolymerized Polypropylene Pipe
The study investigated the changes in random copolymerized polypropylene pipe(PPR pipe)after contacting with polyurethane waterproof coatings and xylene diluents under different conditions.The tensile properties and thermal properties of PPR pipe were measured,and the impacts of polyurethane waterproof coatings and xylene diluents on the properties of PPR pipe were discussed.The results show that small organic molecules of polyurethane waterproof coatings and xylene diluents penetrate into the PPR pipes,reducing the yield strength and elongation at break of the PPR pipes.Small organic molecules from polyurethane waterproof coatings penetrate into the gaps between the molecular chain of the PPR pipe,increasing the volume between the molecular chain segments.The xylene diluent accelerates the penetration of small organic molecules from polyurethane waterproof coatings.The swelling of the PPR pipe is more obvious,and the loss of mechanical strength increases.The small organic molecules have an adverse effect on the oxidation resistance of PPR pipe.When the polyurethane waterproof coatings directly contact PPR,the small organic molecules from the polyurethane waterproof coatings will penetrate into the PPR pipe,affecting the mechanical properties and oxidation resistance of the PPR pipes.

Polyurethane waterproof coatingPPR pipeXyleneCorrosion resistance

余巧玲、陈志锋、王万卷、李晓增、何国山、刘志健、容腾

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广州质量监督检测研究院,广东 广州 511447

广州市NQI-质量安全科技协同创新中心,广东 广州 511447

聚氨酯防水涂料 PPR管 二甲苯 腐蚀性

广州市科技计划项目

2023B04J0407

2024

塑料科技
大连塑料研究所有限公司 深圳市塑胶行业协会

塑料科技

CSTPCD北大核心
影响因子:0.553
ISSN:1005-3360
年,卷(期):2024.52(1)
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