首页|聚乳酸/rGO/HTPDMS纳米纤维膜制备及其性能研究

聚乳酸/rGO/HTPDMS纳米纤维膜制备及其性能研究

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为了减小废弃油水对环境的危害,将聚乳酸-还原氧化石墨烯(PLA/rGO)与羟基封端聚二甲基硅氧烷(HTPDMS)以不同比例共混,通过静电纺丝技术制备了一系列PLA/rGO/HTPDMS复合纤维膜,结合扫描电子显微镜、红外光谱仪和接触角仪等对纤维膜的微观形貌、表面成分和疏水性进行表征。结果表明:PLA/rGO与HTPDMS共混后,所制得的纤维膜均以纳米尺度纤维构成,且膜中存在HTPDMS成分。HTPDMS的加入使PLA/rGO膜疏水性得到大幅提升。油-水混合物的分离具有较高油通量,通量均高于18 400 L/(m2·h),分离效率大于98。2%。经过10次循环分离后纤维膜分离效率仍可达到97%以上,具有良好循环稳定性。PLA/rGO/HTPDMS纤维膜在含油废水处理方面具有广阔的应用前景。
Preparation and Properties of PLA/rGO/HTPDMS Nanofiber Membranes
In order to reduce the environmental hazard of waste oil water,the composite nanofibrous membranes were fabricated by electrospinning technique.The membranes were prepared by blending poly(lactic acid)/reduced graphene oxide(PLA/rGO)and hydroxyl-capped polydimethylsiloxane(HTPDMS)in varying ratios.The nanofibrous membranes were subjected to characterization by a scanning electron microscopy,an infrared spectroscopy,and a contact angle instrument to assess their micro-morphology,surface composition,and hydrophobicity.The results show that the addition of HTPDMS into PLA/rGO results in the formation of membranes consisting of nano-scaled fibres with HTPDMS.The hydrophobicity of PLA/rGO membrane is greatly improved by the addition of HTPDMS.The separation of oil-water mixtures has high oil fluxes,the fluxes are higher than 18 400 L/(m2·h),and the separation efficiency is greater than 98.2%.After 10 cycles of separation,the separation efficiency of fiber membrane can still reach more than 97%,with good cycle stability.PLA/rGO/HTPDMS fiber membrane has a broad application prospect in oily wastewater treatment.

Poly(lactic acid)Reduced graphene oxideHydroxy-terminated polydimethylsiloxaneElectrospinning

秦杰、耿鑫、靳开朗、邓曼娜、王浩、张晓丽、焦晨璐、韩晓建

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安徽农业大学材料与化学学院,安徽合肥 230036

聚乳酸 还原氧化石墨烯 羟基封端聚二甲基硅氧烷 静电纺丝

安徽省教育厅高等学校自然科学研究项目安徽省高等学校省级质量工程项目

KJ2021A01302022jyxm

2024

塑料科技
大连塑料研究所有限公司 深圳市塑胶行业协会

塑料科技

CSTPCD北大核心
影响因子:0.553
ISSN:1005-3360
年,卷(期):2024.52(4)
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