塑料科技2024,Vol.52Issue(5) :121-125.DOI:10.15925/j.cnki.issn1005-3360.2024.05.027

蒙脱土/聚氨酯纳米复合材料降解的研究

Degradation Studies of Montmorillonite/Polyurethane Nanocomposites

李洪涛 韦佳怡 顾晓华 刘家宝
塑料科技2024,Vol.52Issue(5) :121-125.DOI:10.15925/j.cnki.issn1005-3360.2024.05.027

蒙脱土/聚氨酯纳米复合材料降解的研究

Degradation Studies of Montmorillonite/Polyurethane Nanocomposites

李洪涛 1韦佳怡 2顾晓华 2刘家宝2
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作者信息

  • 1. 中国石油化工股份有限公司天津石化公司,天津 300270
  • 2. 桂林航天工业学院能源与建筑环境学院,广西桂林 541004
  • 折叠

摘要

为达到节能环保,保护环境,实现对固废聚氨酯的研究与利用的目的.利用一缩二丙二醇(PG)和聚乙二醇(PEG)作为双组分二醇的醇解剂,碱金属氢氧化钠作为金属催化剂,蒙脱土(MMT)作为改性剂,利用降解产物重新制备出性能优异的蒙脱土/聚氨酯纳米复合材料,重新制备纳米泡沫材料.并对降解产物和纳米泡沫材料进行一系列测试和分析.结果表明:在m(PG)∶m(PEG)=40∶60,氢氧化钠为1.0 g,蒙脱土加入量为0.3 g时,聚氨酯纳米材料达到最好的降解效果,新制备的纳米泡沫材料的表观密度为0.05 g/cm3,抗压强度为0.41 MPa,此时的纳米泡沫材料导热系数更小,保冷性能更好,达到国家标准的要求.

Abstract

In order to achieve energy saving and environmental protection,the research and utilization of solid waste polyurethane is realized.Using monocomponent di-propylene glycol(PG)and polyethylene glycol(PEG)as the alcoholysis agent of the two-component diols,alkali metal sodium hydroxide as the metal catalyst,and montmorillonite clay(MMT)as the modifier,the degradation products were utilized to re-prepare montmorillonite/polyurethane nanocomposites with excellent performance,and to re-prepare nano-foam materials.And a series of tests and analyses were carried out on the degradation products and nanofoam materials.The results show that when m(PG):m(PEG)=40:60,sodium hydroxide is 1.0 g,montmorillonite addition is 0.3 g,the polyurethane nanomaterials can achieve the best degradation effect,the apparent density of the newly prepared nano-foam material is 0.05 g/cm3,the compressive strength is 0.41 MPa.At this time,the nano-foam material has a smaller thermal conductivity and better cold-retaining performance,and meets the requirements of the national standard.

关键词

聚氨酯/金属催化剂/蒙脱土/降解/纳米复合材料

Key words

Polyurethane/Metal catalyst/Montmorillonite/Degradation/Nanocomposites

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出版年

2024
塑料科技
大连塑料研究所有限公司 深圳市塑胶行业协会

塑料科技

CSTPCD北大核心
影响因子:0.553
ISSN:1005-3360
参考文献量16
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