首页|用于公路的丙烯酸酯类聚氨酯/碳纳米管材料的制备与性能分析

用于公路的丙烯酸酯类聚氨酯/碳纳米管材料的制备与性能分析

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为避免公路图标和标识线受到恶劣环境的侵蚀,延长公路图标和标识线使用寿命,研究用于公路的丙烯酸酯类聚氨酯/碳纳米管材料的制备与性能分析.采用异佛尔酮-二异氰酸酯、偶氮二异丁腈等材料制备实验用丙烯酸酯类聚氨酯,分别在其中添加质量分数为0.2%、0.4%以及0.6%酸化处理后的碳纳米管,制成3种不同碳纳米管掺量的试样,通过力学性能测试以及耐磨性测试分析每种试样的应用效果.结果表明:当碳纳米管质量分数为0.2%时,材料的力学性能及耐磨性较弱,可见添加较少的碳纳米管无法提高材料性能;当碳纳米管掺量达到0.6%时,材料基础性能明显低于碳纳米管质量分数为0.4%时的试样.在不同方法测试下,添加质量分数0.4%碳纳米管的试样可以保持优异的热稳定性,当处于高温状态时,材料的拉伸强度和撕裂强度均保持较高水平,且磨损率相对较低.因此,添加质量分数0.4%碳纳米管的丙烯酸酯类聚氨酯更适用于公路建设.
Preparation and Properties Analysis of Acrylic Polyurethane/Carbon Nanotube Materials for Highway Applications
To avoid the erosion of highway icons and signage lines by harsh environments and extend their service life,the preparation and performance analysis of acrylic polyurethane/carbon nanotube materials for highways were studied.Experimental acrylic polyurethane was prepared using materials such as isophorone diisocyanate and azobisisobutyronitrile.Carbon nanotubes with mass fractions of 0.2%,0.4%and 0.6%after acidification treatment were added to the polyurethane,and three different carbon nanotube dosages were prepared as samples.The application effects of each sample were analyzed through a mechanical property test and a wear resistance test.The results show that when the mass fraction of carbon nanotubes is 0.2%,the mechanical properties and wear resistance of the materials are weak,indicating that adding fewer carbon nanotubes cannot improve material quality.When the carbon nanotube mass fraction reaches 0.6%,its basic performance is significantly lower than that of the sample with a carbon nanotube mass fraction of 0.4%.Under different testing methods,the sample with 0.4%mass fraction carbon nanotubes added can maintain excellent thermal stability.The tensile strength and tear strength of the materials are at a high level in a high temperature state,and the wear rate is relatively low.Therefore,acrylic polyurethane with 0.4%mass fraction of carbon nanotubes added is more suitable for highway construction.

AcrylatesCarbon nanotubesMechanical propertieswear resistance

吕东滨、杨洋、李斌

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广西钟贺高速公路有限公司,广西 贺州 542800

广西交通职业技术学院,广西 南宁 530214

兰州交通大学,甘肃 兰州 730070

丙烯酸酯类 碳纳米管 力学性能 耐磨性

2024

塑料科技
大连塑料研究所有限公司 深圳市塑胶行业协会

塑料科技

CSTPCD北大核心
影响因子:0.553
ISSN:1005-3360
年,卷(期):2024.52(11)