摘要
近年来,金属有机框架(MOFs)构建的荧光探针因其在传感领域展现出的卓越性能而备受瞩目.这类荧光探针不仅有效弥补了传统检测技术的诸多不足,还兼具成本低、操作简便、可视化程度高及灵敏度高等显著优势,已广泛应用于传感技术研究.本文系统回顾了近年来国内外在金属有机框架及其复合材料作为荧光探针应用于离子传感方面的研究进展.详细阐述了 MOFs及其复合材料荧光探针的设计策略、结构特征、发光特性以及传感机理,并对MOFs类荧光探针的未来发展趋势进行了深入分析与展望.
Abstract
In recent years,fluorescent probes constructed from metal-organic frameworks(MOFs)have attracted considerable attention due to their excellent performance in the field of sensing.These fluorescent probes not only effectively compensate for many shortcomings of traditional detection techniques but also possess notable advantages such as low cost,ease of operation,high visualization,and high sensitivity,making them widely used in sensing technology research.This paper systematically reviews the recent domestic and international research progress on the application of MOFs and their composites as fluorescent probes in ion sensing.The design strategies,structural characteristics,luminescent properties,and sensing mechanisms of MOFs and their composite fluorescent probes are elaborated in detail,and an in-depth analysis and outlook on the future development trends of MOF-based fluorescent probes are provided.