吉林师范大学学报(自然科学版)2025,Vol.46Issue(1) :38-42.DOI:10.16862/j.cnki.issn1674-3873.2025.01.006

BiVO4/Ag/Cu2O纳米复合材料的制备及其对四环素的光催化性能研究

Preparation of BiVO4/Ag/Cu2O nanocomposites and their photocatalytic activity for tetracycline degradation

马冲亚 刘福祺 何浩诚 王晓涵 赵文诗
吉林师范大学学报(自然科学版)2025,Vol.46Issue(1) :38-42.DOI:10.16862/j.cnki.issn1674-3873.2025.01.006

BiVO4/Ag/Cu2O纳米复合材料的制备及其对四环素的光催化性能研究

Preparation of BiVO4/Ag/Cu2O nanocomposites and their photocatalytic activity for tetracycline degradation

马冲亚 1刘福祺 1何浩诚 2王晓涵 2赵文诗2
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作者信息

  • 1. 吉林师范大学地理科学与旅游学院,吉林四平 136000
  • 2. 吉林师范大学物理学院,吉林四平 136000
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摘要

采用水热法和湿化学还原法成功合成了 BiVO4纳米晶体、BiVO4/Cu2O和BiVO4/Ag/Cu2O纳米复合材料,并利用X射线衍射仪(XRD)、场发射扫描电子显微镜(SEM)和紫外-可见分光光度计(UV-Vis)对三组样品的结构、微观形貌及其四环素的光催化降解效果进行了分析.结果表明:Cu2O和Ag纳米晶体成功附着在形状近似十面体的BiVO4纳米晶体的表面;BiVO4纳米晶体、BiVO4/Cu2O和BiVO4/Ag/Cu2O纳米复合材料对四环素展现出不同程度的降解效果,其中BiVO4/Ag/Cu2O纳米复合材料的光催化性能最强,且循环6次后仍保持优异的光催化性能.本研究为光催化剂的优化提供了新的思路,并在处理有机废水方面展现出广阔的应用前景.

Abstract

BiVO4 nanocrystals,BiVO4/Cu2O and BiVO4/Ag/Cu2O nanocomposites were successfully synthesized using hydrothermal and wet chemical reduction methods.X-ray diffraction(XRD),field emission scanning electron microscopy(SEM)and UV-Vis spectrophotometer were used to analyze the structure,microstructure and the photocatalytic degradation effect towards tetracycline of the three samples.Experimental results indicate that Cu2O and Ag nanocrystals are successfully attached to the surfaces of BiVO4 nanocrystals with similar decahedral shape.BiVO4 nanocrystals,BiVO4/Cu2O and BiVO4/Ag/Cu2O nanocomposites show different degradation effects towards tetracycline.Among them,BiVO4/Ag/Cu2O nanocomposites exhibit the strongest photocatalytic performance and maintain excellent catalytic performance even after six cycles.This study provides a new idea for the optimization of photocatalyst and shows a broad application prospect in the treatment of organic wastewater.

关键词

BiVO4/Ag/Cu2O纳米复合材料/四环素/光催化降解

Key words

BiVO4/Ag/Cu2O nanocomposites/tetracycline/photocatalytic degradation

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出版年

2025
吉林师范大学学报(自然科学版)
吉林师范大学

吉林师范大学学报(自然科学版)

影响因子:0.397
ISSN:1674-3873
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