首页|豆芽中4-氯苯氧乙酸钠和6-苄基腺嘌呤残留的降解规律研究

豆芽中4-氯苯氧乙酸钠和6-苄基腺嘌呤残留的降解规律研究

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目的:研究豆芽中植物生长调节剂 4-氯苯氧乙酸钠和 6-苄基腺嘌呤的降解规律.方法:通过超高效液相色谱-串联质谱法,以未检出 4-氯苯氧乙酸钠和 6-苄基腺嘌呤的黄豆芽、绿豆芽为空白基质,采用加标回收试验研究样品在冷藏和冷冻条件下 4-氯苯氧乙酸钠和 6-苄基腺嘌呤的动态残留量.结果:冷冻条件下,黄豆芽、绿豆芽中 4-氯苯氧乙酸钠降解半衰期分别为 44.1 d、90.0 d,6-苄基腺嘌呤降解半衰期分别为32.4 d、40.8 d.冷藏条件下,黄豆芽、绿豆芽中4-氯苯氧乙酸钠降解半衰期分别为37.5 d、45.3 d,6-苄基腺嘌呤降解半衰期分别为11.8 d、31.8 d.结论:该研究为豆芽中 4-氯苯氧乙酸和 6-苄基腺嘌呤因自身降解造成初检结论被推翻的情况提供了理论参考.
Degradation Rules Study of 4-Chlorophenxyacetate and 6-Benzylaminopurine in Bean Sprouts
Objective:To study the residues degradation rule of plant growth regulators 4-chlorophenxyacetate and 6-benzylaminopurine in bean sprout.Method:The ultra-high performance liquid chromatography-tandem mass spectrometry method was used to study the dynamic residues of sodium 4-chlorophenoxyacetate and 6-benzyladenine in soybean sprouts under refrigeration and freezing conditions by standard addition recovery test,and soybean sprouts and mung bean sprouts without detected 4-chlorophenoxyacetic acid sodium and 6-benzyladenine were used as blank matrices.Result:Under freezing conditions,the degradation half-lives of 4-chlorophenxyacetate in soybean sprouts and mung bean sprouts were 44.1 d and 90.0 d,respectively,and the degradation half-lives of 6-benzylaminopurine were 32.4 d and 40.8 d,respectively.Under cold storage conditions,the degradation half-lives of 4-chlorophenxyacetate in soybean sprouts and mung bean sprouts were 37.5 d and 45.3 d,respectively,and the degradation half-lives of 6-benzylaminopurine were 11.8 d and 31.8 d,respectively.Conclusion:The study provide a theoretical study on the situation that the preliminary detection conclusion is overturned due to the degradation of bean sprouts itself.

bean sproutsdegradationultra-high performance liquid chromatography-tandem mass spectrometry4-chlorophenxyacetate6-benzylaminopurine

黄彬彬、王小珍、裴黎艳、覃斌、黄春燕、黄镜洲

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钦州市检验检测中心,广西钦州 535000

广西钦州星河食品有限公司 广西钦州 535000

豆芽 降解 超高效液相色谱-串联质谱法 4-氯苯氧乙酸钠 6-苄基腺嘌呤

广西壮族自治区市场监督管理局科技项目

GSJKJZC2022-20

2024

食品安全导刊
商业科技质量中心 北京肉类食品协会

食品安全导刊

影响因子:0.065
ISSN:1674-0270
年,卷(期):2024.(7)
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