首页|离子色谱法测定天然矿泉水中4种无机阴离子

离子色谱法测定天然矿泉水中4种无机阴离子

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目的:建立一种同时检测天然矿泉水中 4 种无机阴离子含量的方法.方法:待测样品经0.45 μm水系过滤膜过滤后,采用Metrosep A Supp 5 Guard/4.0保护柱以及Metrosep A Supp 5阴离子分离柱分离,8 mmol·L-1 碳酸氢钠水溶液作为淋洗液进行等度淋洗,流速为 1.0 mL·min-1,电导检测器进行检测.结果:4 种无机阴离子在一定浓度范围内线性关系较好,相关系数均在 0.996 0 以上,检出限在0.000 1~0.010 0 mg·L-1,定量限在 0.000 4~0.040 0 mg·L-1;相对标准偏差在0.59%~8.16%,加标回收率在80.00%~112.50%.结论:该方法具有灵敏度高、分离度好、准确度强等优势,适用于天然矿泉水中F-、Cl-、NO3-和SO42-的快速定量检测.
Determination of 4 Inorganic Anions in Natural Mineral Water by Ion Chromatography
Objective:To establish a method for simultaneous determination of 4 kinds of inorganic anions in natural mineral water.Method:After being filtered by 0.45 μm aqueous filtration membrane,the samples were separated by Metrosep A Supp 5 Guard/4.0 protective column and Metrosep A Supp 5 anion separation column,and 8 mmol·L-1 sodium bicarbonate aqueous solution was used as the leach solution for equal degree leaching.The flow rate was 1.0 mL·min-1,and the conductivity detector was used for detection.Result:The correlation coefficients were above 0.996 0,the detection limit was 0.000 1~0.010 0 mg·L-1,and the quantitation limit was 0.000 4~0.040 0 mg·L-1.The relative standard deviations were 0.59%~8.16%,and the recoveries were 80.00%~112.50% .Conclusion:The method has the advantages of high sensitivity,good separation and high accuracy,and is suitable for the rapid quantitative determination of F-,Cl-,NO3-and SO42-in natural mineral water.

ion chromatographynatural mineral waterinorganic anion

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广东省汕尾市质量计量监督检测所,广东汕尾 516600

离子色谱法 天然矿泉水 无机阴离子

2024

食品安全导刊
商业科技质量中心 北京肉类食品协会

食品安全导刊

影响因子:0.065
ISSN:1674-0270
年,卷(期):2024.(24)